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4,4'-Methylenedianiline (101-77-9)

Identification
Name:4,4'-Methylenedianiline
CAS:101-77-9
EINECS: 202-974-4
Molecular Formula: C13H14N2
Molecular Weight: 198.27
InChI: InChI=1/C13H14N2/c14-12-5-1-10(2-6-12)9-11-3-7-13(15)8-4-11/h1-8H,9,14-15H2
Molecular Structure: (C13H14N2) 4,4'-methylenedianiline; ,4'-Methylenebisaniline; 4-(4-Aminobenzyl)phenylamine; 4,4'-diaminodiphenyl...
Properties
Transport:UN 2651
Density:1.15
Stability:Stable under normal temperatures and pressures.
Water Solubility:Slightly soluble.
Solubility:Slightly soluble. <0.1 g/100 mL at 19 oC
Appearance:white to yellow or beige flakes or crystals
Specification:

  4,4'-Methylenedianiline , its cas register number is 101-77-9. It also can be called 4,4'-Diaminodiphenylmethan ; 4,4'-Methylenebis(benzeneamine) ; 4-(4-Aminobenzyl)aniline ; Ancamine TL ; Aniline, 4,4'-methylenedi- ; Benzenamine, 4,4'-methylenebis- ; Bis(4-aminophenyl)methane ; Bis-p-aminofenylmethan ; Curithane ; Dadpm ; Di-(4-aminophenyl)methane ;
 Diaminodiphenylmethane ; Methylenebis(aniline) ; Sumicure M ; p,p'-Diaminodifenylmethan ; p,p'-Methylenedianiline ; p-Toluidine, alpha-(p-aminophenyl)- .

Report:

NTP 10th Report on Carcinogens. IARC Cancer Review: Group 2B IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 ,1987,p. 56.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Sufficient Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 39 ,1986,p. 347.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Inadequate Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 4 ,1974,p. 79.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . Community Right-To-Know List. Reported in EPA TSCA Inventory.

Packinggroup: III
Storage Temperature: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Color: Crystals from water or benzene
Tan flakes, lumps, or pearly leaflets from benzene
Plates or needles (water); plates (benzene)
Light-brown crystals
Light tan to white crystalline solid
Usage:Determination of tungsten & sulfates, as corrosion inhibitor, prepn of azo dyes.
Safety Data
Hazard Symbols T:Toxic N:Dangerousfortheenvironment
 

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