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4H-4a,7-Methanooxazirino[3,2-i][2,1]benzisothiazole,tetrahydro-9,9-dimethyl-, 3,3-dioxide, (4aS,7R,8aS)- (104322-63-6)

Identification
Name:4H-4a,7-Methanooxazirino[3,2-i][2,1]benzisothiazole,tetrahydro-9,9-dimethyl-, 3,3-dioxide, (4aS,7R,8aS)-
Synonyms:4H-4a,7-Methanooxazirino[3,2-i][2,1]benzisothiazole,tetrahydro-9,9-dimethyl-, 3,3-dioxide, [4aS-(4aa,7a,8aR*)]-;(+)-(Camphorsulfonyl)oxaziridine;(+)-(Camphorylsulfonyl)oxaziridine;Davis' chiral oxaziridine;
CAS:104322-63-6
Molecular Formula: C10H15NO3S
Molecular Weight: 229.30
InChI: InChI=1/C10H15NO3S/c1-8(2)7-3-4-9(8)6-15(12,13)11-10(9,5-7)14-11/h7H,3-6H2,1-2H3/t7-,9+,10+,11?/m1/s1
Molecular Structure: (C10H15NO3S) 4H-4a,7-Methanooxazirino[3,2-i][2,1]benzisothiazole,tetrahydro-9,9-dimethyl-, 3,3-dioxide, [4aS-(4aa...
Properties
Melting Point: 172-174 ºC
Flash Point: 145.9°C
Boiling Point: 317.6°Cat760mmHg
Density:1.49g/cm3
Refractive index:1.63
Alpha:45 º (C=2, CHLOROFORM)
Appearance:white crystall powder
Flash Point: 145.9°C
Storage Temperature: 2-8°C
Usage:

 (1S)-(+)-(10-Camphorsulfonyl)oxaziridine (CAS NO.104322-63-6) is a useful synthetic intermediate.It is used for asymmetric hydroxylation.

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