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4-Morpholinecarboxylicacid, 6-oxo-2,3-diphenyl-, 1,1-dimethylethyl ester, (2S,3R)- (112741-50-1)

Identification
Name:4-Morpholinecarboxylicacid, 6-oxo-2,3-diphenyl-, 1,1-dimethylethyl ester, (2S,3R)-
Synonyms:(5S,6R)-4-tert-Butoxycarbonyl-5,6-diphenylmorpholin-2-one;(2S,3R)-tert-Butyl 6-oxo-2,3- diphenylmorpholine-4-carboxylate;4-Morpholinecarboxylicacid, 6-oxo-2,3-diphenyl-, 1,1-dimethylethyl ester, (2S-cis)-;
CAS:112741-50-1
Molecular Formula: C21H23NO4
Molecular Weight: 353.42
InChI: InChI=1/C21H23NO4/c1-21(2,3)26-20(24)22-14-17(23)25-19(16-12-8-5-9-13-16)18(22)15-10-6-4-7-11-15/h4-13,18-19H,14H2,1-3H3
Molecular Structure: (C21H23NO4) (5S,6R)-4-tert-Butoxycarbonyl-5,6-diphenylmorpholin-2-one;(2S,3R)-tert-Butyl 6-oxo-2,3- diphenylmorp...
Properties
Flash Point: 262 ºC
Boiling Point: 509.6ºC at 760 mmHg
Density:1.175 g/cm3
Refractive index:1.561
Alpha:86 º (C=5.5 IN METHYLENE CHLORIDE)
Appearance:WHITE POWDER
Specification:

The IUPAC name of 4-Morpholinecarboxylicacid, 6-oxo-2,3-diphenyl-, 1,1-dimethylethyl ester, (2S,3R)- is tert-butyl (2S,3R)-6-oxo-2,3-diphenylmorpholine-4-carboxylate. With the CAS registry number 112741-50-1, it is also named as (2S,3R)-tert-Butyl 6-oxo-2,3- diphenylmorpholine-4-carboxylate. The product's categories are API intermediates; Chiral Building Blocks; Heterocyclic Building Blocks; Morpholines. Besides, it is white powder, which should be stored in sealed container in a cool, dry place at 2-8 °C. And you should ensure that the workplaces have good ventilated or exhaust device.

The other characteristics of 4-Morpholinecarboxylicacid, 6-oxo-2,3-diphenyl-, 1,1-dimethylethyl ester, (2S,3R)- can be summarized as: (1)ACD/LogP: 3.45; (2)# of Rule of 5 Violations: 0; (3)H bond acceptors: 5; (4)H bond donors: 0; (5)Freely Rotating Bonds: 4; (6)Polar Surface Area: 55.84 Å2; (7)Index of Refraction: 1.561; (8)Molar Refractivity: 97.45 cm3; (9)Molar Volume: 300.6 cm3; (10)Polarizability: 38.63×10-24cm3; (11)Surface Tension: 44.8 dyne/cm; (12)Density: 1.175 g/cm3; (13)Flash Point: 262 °C; (14)Melting point: 206 °C; (15)alpha: 86 °(c=5.5 in methylene chloride); (16)Enthalpy of Vaporization: 78.02 kJ/mol; (17)Boiling Point: 509.6 °C at 760 mmHg; (18)Vapour Pressure: 1.67E-10 mmHg at 25 °C.

When you are using this chemical, please be cautious about it as the following: it is irritating to eyes, respiratory system and skin. You should wear suitable gloves and eye/face protection when use it. Moreover, in case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

People can use the following data to convert to the molecule structure.
(1)SMILES:O=C2O[C@@H](c1ccccc1)[C@H](N(C(=O)OC(C)(C)C)C2)c3ccccc3
(2)InChI:InChI=1/C21H23NO4/c1-21(2,3)26-20(24)22-14-17(23)25-19(16-12-8-5-9-13-16)18(22)15-10-6-4-7-11-15/h4-13,18-19H,14H2,1-3H3/t18-,19+/m1/s1
(3)InChIKey:MRUKRSQUUNYOFK-MOPGFXCFBO
(4)Std. InChI:InChI=1S/C21H23NO4/c1-21(2,3)26-20(24)22-14-17(23)25-19(16-12-8-5-9-13-16)18(22)15-10-6-4-7-11-15/h4-13,18-19H,14H2,1-3H3/t18-,19+/m1/s1
(5)Std. InChIKey:MRUKRSQUUNYOFK-MOPGFXCFSA-N

Flash Point: 262 ºC
Safety Data
Hazard Symbols Xi:Irritant
 

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