Specification: |
Rhenium trichloride prepared from rhenium pentachloride without further treatment is chemically reactive, but if it is vacuum sublimed at 500oC, then it becomes comparatively unreactive. However, x-ray diffraction tests show no observable difference in structure between the untreated and vacuum sublimed material.
The heat of oxidation according to the equation,
ReCl3(s) + 4OH- + 2OCl- → ReO4- + 2H2O + 5Cl-
is 190.7 ± 0.2 kcal/mol.
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