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Chlorine perchlorate , its cas register number is 27218-16-2. It also can be called Chlorine perchlorate is the chemical compound with the formula Cl2O4. This chlorine oxide is an asymmetric oxide, with one chlorine atom in oxidation state +1 and the other +7, with proper formula ClOClO3.
2 ClO2 + UV(λ=436nm) → ClOClO3
Chlorine perchlorate reacts with metal chlorides forming anhydrous perchlorates:
CrO2Cl2 + 2ClOClO3 → 2Cl2 + CrO2(ClO4)2
TiCl4 + 4ClOClO3 → 4Cl2 + Ti(ClO4)4
Chlorine perchlorate (CAS NO.27218-16-2) is pale greenish liquid which decomposes at room temperature. When heated to decomposition it emits toxic fumes of Cl−.
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