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2-Nitro-1,4-Phenylenediamine (5307-14-2)

Identification
Name:2-Nitro-1,4-Phenylenediamine
Synonyms:1,4-Diamino-2-nitrobenzene; 2-n-p-pda; 2-NDB; 2-nitro-1,4-Benzenediamine; 2-nitro-1,4-diaminobenzene; o-Nitro-p-phenylenediamine; 2-NPPD; 4-Amino-2-nitroaniline; C.I. 76070; C.I. oxidation base 22; durafur brown; durafur brown 2R; Dye gs; fouramine 2R; fourrine 36; fourrine brown 2R; nitro-p-phenylenediamine; oxidation base 22; ursol brown rr; zoba brown rr; 2-Nirtro-p-phenylene diamine;
CAS:5307-14-2
EINECS: 226-164-5
Molecular Formula: C6H7N3O2
Molecular Weight: 153.14
InChI: InChI=1/C6H7N3O2/c7-4-1-2-5(8)6(3-4)9(10)11/h1-3H,7-8H2
Molecular Structure: (C6H7N3O2) 1,4-Diamino-2-nitrobenzene; 2-n-p-pda; 2-NDB; 2-nitro-1,4-Benzenediamine; 2-nitro-1,4-diaminobenzene...
Properties
Transport:3143
Density:1.446g/cm3
Stability:Stable. Incompatible with strong oxidizing agents.
Refractive index:1.699
Water Solubility:<0.1 g/100 mL at 22 ºC
Solubility:<0.1 g/100 mL at 22 oC
Appearance:Almost black needles with dark-green lustre.
Specification:

First Aid Measures of 1,4-Diamino-2-nitrobenzene(5307-14-2):
Skin:Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Remove contaminated clothing and shoes.
Eyes:Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Ingestion:If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.

Storage of 1,4-Diamino-2-nitrobenzene(5307-14-2):
Store in a cool, dry, well-ventilated area away from incompatible substances. Keep containers tightly closed.

Report:

IARC Cancer Review: Group 3 IMEMDT ?? IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 (1987),p. 56.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.:?) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Inadequate Evidence IMEMDT ?? IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 16 (1978),p. 73.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.:?) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . NCI Carcinogenesis Bioassay (feed); No Evidence: rat NCITR* ?? National Cancer Institute Carcinogenesis Technical Report Series. (Bethesda, MD 20014) No. NCI-CG-TR-169 ,1979. ; Clear Evidence: mouse NCITR* ?? National Cancer Institute Carcinogenesis Technical Report Series. (Bethesda, MD 20014) No. NCI-CG-TR-169 ,1979. . Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program.

Packinggroup: I; II; III
HS Code: 29215119
Storage Temperature: Store in a cool, dry, well-ventilated area away from incompatible substances. Keep containers tightly closed.
Color: Almost black needles with dark-green luster
Usage:

In dyeing furs brown and reddish brown.

Safety Data
Hazard Symbols Xn:Harmful