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Thionyl fluoride (7783-42-8)

Identification
Name:Thionyl fluoride
Synonyms:Sulfurdifluoride monoxide; Sulfur difluoride oxide; Sulfur fluoride oxide (SF2O);Sulfur oxide fluoride (SOF2); Sulfur oxyfluoride (SOF2); Sulfurous oxyfluoride;Thionyl difluoride
CAS:7783-42-8
EINECS: 231-997-2
Molecular Formula: F2O S
Molecular Weight: 86.06
InChI: InChI=1/F2OS/c1-4(2)3
Molecular Structure: (F2OS) Sulfurdifluoride monoxide; Sulfur difluoride oxide; Sulfur fluoride oxide (SF2O);Sulfur oxide fluori...
Properties
Transport:3308
Melting Point: -110.5 C
Flash Point: °C
Boiling Point: °Cat760mmHg
Density:1.758g/cm3
Stability:Reacts with water. Decomposes on heating.
Refractive index:1.376
Water Solubility:reacts Stability Reacts with water. Decomposes on heating.Toxicology Irritant. Causes pulmonary oedema at high concentration. Toxicity data (The meaning of any toxicol
Solubility:reacts

Appearance:Colorless gas
Specification:

 Thionyl fluoride (CAS NO.7783-42-8) is also called Fluorure de thionyle ; Fluorure de thionyle [French] ; Sulfur difluoride monoxide ; Sulfur difluoride oxide ; Sulfurous oxyfluoride ; Thionyl difluoride . Thionyl fluoride (CAS NO.7783-42-8) is the inorganic compound with the formula SOF2. This colourless gas is mainly of theoretical interest, but it is a product of the degradation of sulfur hexafluoride, an insulator in electrical equipment. The molecule adopts a pyramidal structure, with C2v symmetry. The S-O and S-F distances are 1.42 and 1.58 A, respectively. The O-S-F and F-S-F angles are 106.2 and 92.2°, respectively. Thionyl chloride and thionyl bromide have similar structures, although these compounds are liquid at room temperature. Mixed halides are also known, such as SOClF. Thionyl fluoride (CAS NO.7783-42-8)  can react with water. It will decompose on heating.

Report:

Reported in EPA TSCA Inventory.

Flash Point: °C
Safety Data