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(+/-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl

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[Flash Point]

419
[Fire Fighting]

Use water spray, dry chemical, carbon dioxide, or chemical foam. Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
[Ingestion]

Get medical aid. Wash mouth out with water.
[Inhalation]

Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
[Skin]

Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
[Eyes]

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
[Storage]

Store in a cool, dry place. Store in a tightly closed container.
[Ingestion]

May cause irritation of the digestive tract. May be harmful if swallowed.
[Inhalation]

Causes respiratory tract irritation. May be harmful if inhaled.
[Skin]

Causes skin irritation. May be harmful if absorbed through the skin.
[Eyes]

Causes eye irritation.
[EC Risk Phrase]

R 36/37/38
[EC Safety Phrase]

S 26 37/39
[Personal Protection]

Wear appropriate protective gloves to prevent skin exposure. ear appropriate protective clothing to prevent skin exposure. Chemical safety goggles.
[Respirators]

Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
[Appearance]

Solid
[Solubility in water]

Insoluble
[Melting Point]

280 - 285
[Boiling Point]

724
[Vapor Pressure]

5.6E-20 (25 C)
[Partition Coefficient]

13.38
[Heat Of Vaporization]

102.0 kJ/mol
[Usage]

Chiral ligand for metal mediated asymmetric catalysis.
[Product Name]

2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl
[Synonyms]

(+/-)-2,2-bis(Diphenylphosphino)-1,1-dinaphthyl
2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl
[CAS]

"CASEN_98327-87-8.htm">98327-87-8
[Formula]

C44H32P2
[Molecular Weight]

622.69000000000005
[Merck]

12,10504
[Beilstein/Gmelin]

5321443
[Beilstein Reference]

6-16
[Small spills/leaks]

Vacuum or sweep up material and place into a suitable disposal container.
[Stability]

Stable under normal temperatures and pressures.
[Incompatibilities]

Strong oxidizers, air.
[Decomposition]

Carbon monoxide, oxides of phosphorus, carbon dioxide.