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trans-1,4-Dichloro-2-butene

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[Flash Point]

54
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.
[Upper exp. limit]

4
[Lower exp. limit]

1.5
[Fire Potential]

Flammable dichlorobutene
[Ingestion]

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. SPEED IS ESSENTIAL. A DOCTOR MUST BE NOTIFIED AT ONCE.
[Inhalation]

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
[Skin]

Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
[Eyes]

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
[Storage]

Keep away from sources of ignition. Store in a tightly closed container. Store in a dry area. Keep under an argon blanket. Refrigerator (approx 4 C).
[Handling]

Use spark-proof tools and explosion proof equipment. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
[Inhalation]

May be fatal if inhaled. Causes chemical burns to the respiratory tract. May cause abdominal pain, nausea, vomiting, and inflammation of the gums and mouth.
[Skin]

Causes skin burns. Toxic in contact with skin.
[Eyes]

Causes eye burns. Lachrymator.
[Ingestion]

Poison by ingestion. Causes gastrointestinal tract burns.
[Hazards]

The material will burn, though it may require some effort to ignite. Fire produces irritating and poisonous gases. When heated to decomposition, it emits toxic fumes of chlorine-containing compounds.
[UN (DOT)]

2927
[Personal Protection]

Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
[Respirators]

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
[Exposure Effects]

May cause cancer in humans.
[Appearance]

Colorless liquid with a distinct odor.
[Solubility in water]

Slightly soluble
[Melting Point]

1
[Boiling Point]

156
[Vapor Pressure]

3.9 (25 C)
[Density]

1.1873 g/cm3 (20 C)
[Heat Of Vaporization]

37.6 kJ/mol
[Heat Of Combustion]

-5063 kJ/mol
[Usage]

Chemical intermediate for hexamethylenediamine & chloroprene.
[Refractive Index]

1.4870 (20 C)
[Product Name]

(E)-1,4-Dichloro-2-butene
[Synonyms]

1,4-Dichloro-trans-2-butene
2-Butene, 1,4-dichloro-, (2E)-
trans-1,4-Dichlorobuten-2-ene
[CAS]

"CASEN_110-57-6.htm">110-57-6
[Formula]

C4H6Cl2
[Molecular Weight]

125
[EINECS]

203-779-7
[RTECS]

EM4903000
[RTECS Class]

Tumorigen
[Beilstein/Gmelin]

1719693
[Beilstein Reference]

4-01-00-00787
[Small spills/leaks]

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Remove all sources of ignition. Use a spark-proof tool.
[Stability]

Reacts slowly with water to form hydrochloric acid.
[Incompatibilities]

Strong oxidizing agents, strong bases.
[Decomposition]

Hydrogen chloride, carbon monoxide, carbon dioxide.
[Combustion Products]

Fire may produce irritating, corrosive and/or toxic gases.
[UN Number]

2927
[Hazard Class]

6.1
[Packing Group]

I; II