| [Flash Point] 132 | |
| [Flash Point] 51 | |
| [Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire, use carbon dioxide, dry chemical powder or appropriate foam. | |
| [Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Extinguishing media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Water may be ineffective. Do NOT get water inside containers. Do NOT use straight streams of water. Cool containers with flooding quantities of water until well after fire is out. | |
| [Upper exp. limit] 14.4 | |
| [Lower exp. limit] 2.1 | |
| [Fire Potential] HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. | |
| [Fire Potential] This compound is combustible. | |
| [Ingestion] Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid. | |
| [Ingestion] May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Ingestion of large amounts may cause CNS depression. | |
| [Ingestion] Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. | |
| [Inhalation] Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration. | |
| [Inhalation] May cause respiratory tract irritation. Aspiration may lead to pulmonary edema. Vapors may cause dizziness or suffocation. May cause burning sensation in the chest. | |
| [Inhalation] Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Do not use mouth-to-mouth respiration if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. | |
| [Skin] May cause irritation and dermatitis. May cause cyanosis of the extremities. | |
| [Skin] Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. | |
| [Skin] Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. | |
| [Eyes] May cause eye irritation. May cause chemical conjunctivitis and corneal damage. | |
| [Eyes] Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. | |
| [Eyes] Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. | |
| [Storage] Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from water. Flammables-area. Keep containers tightly closed. Store protected from moisture. | |
| [Storage] Keep containers tightly closed. Store in a cool, dry area away from incompatible substances. | |
| [Handling] Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale. Use only in a chemical fume hood. Do not breathe dust. | |
| [Handling] Wash thoroughly after handling. Use only in a well ventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. | |
| [Ingestion] Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May be harmful if swallowed. May cause itching. May cause convulsions and blurred vision. | |
| [Inhalation] May cause nausea, dizziness, and headache. Harmful if inhaled. May cause itching. May cause convulsions and blurred vision. | |
| [Skin] Causes severe skin irritation. May cause itching. | |
| [Eyes] Causes severe eye irritation. | |
| [Hazards] Contact with metals may evolve flammable hydrogen gas. | |
| [Hazards] Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. | |
| [EC Risk Phrase] R 10 36 | |
| [EC Risk Phrase] R 20/21/22 | |
| [EC Safety Phrase] S 16 26 36 | |
| [EC Safety Phrase] S 22 36/37 | |
| [UN (DOT)] 1993 | |
| [UN (DOT)] 2811 | |
| [Personal Protection] Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. | |
| [Personal Protection] Eyes: Wear safety glasses and chemical goggles if splashing is possible. Skin: Wear appropriate protective gloves and clothing to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. | |
| [Respirators] Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. | |
| [Respirators] A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. | |
| [Exposure Effects] Effects may be delayed. | |
| [Exposure limit(s)] NIOSH REL: TWA 6 ppm (20 mg/m3) | |
| [Poison Class] - | |
| [Poison Class] 3 | |
| [Appearance] Colorless to light brown crystals. | |
| [Appearance] Light yellow liquid. | |
| [Solubility in water] Decomposition | |
| [Solubility in water] 130 g/L | |
| [Melting Point] 18 - 20 | |
| [Melting Point] 53 | |
| [Boiling Point] 240 | |
| [Boiling Point] 267 | |
| [Vapor Pressure] 0.01 (25 C) | |
| [Density] 0.9711 g/cm3 (20 C) | |
| [Density] 1.023 g/cm3 (20 C) | |
| [Partition Coefficient] -.99 | |
| [Heat Of Vaporization] 61.6 kJ/mol | |
| [Heat Of Vaporization] 50.7 kJ/mol | |
| [Usage] A universal matrix for solid-state ionic conductors. | |
| [Usage] Heat-resistant surface coatings in paints and plastics. | |
| [Vapor Density] 9.8 | |
| [Vapor Density] 2.1 | |
| [Refractive Index] 1.41496 (60 C) | |
| [Refractive Index] 1.46 (20 C) | |
| [Product Name] Butanedinitrile | |
| [Synonyms] 1,2-Dicyanoethane Butanedinitrile Ethylene cyanide Ethylene dicyanide Isopropyl orthotitanate Isopropyl titanate(IV) Succinic dinitrile Tetraisopropoxide titanium Tetraisopropoxytitanium Tetraisopropyl orthotitanate Tetraisopropyl titanate | |
| [CAS] "CASEN_110-61-2.htm">110-61-2 | |
| [CAS] "CASEN_546-68-9.htm">546-68-9 | |
| [Formula] C12H28O4Ti | |
| [Formula] C4H4N2 | |
| [Molecular Weight] 80.09 | |
| [Molecular Weight] 284.25 | |
| [EINECS] 203-783-9 | |
| [EINECS] 208-909-6 | |
| [RTECS] NT8060000 | |
| [RTECS] WN3850000 | |
| [RTECS Class] Primary Irritant | |
| [RTECS Class] Reproductive Effector | |
| [Merck] 12,9041 | |
| [Merck] 12,9614 | |
| [Beilstein/Gmelin] 1098380 | |
| [Beilstein/Gmelin] 3679474 | |
| [Beilstein Reference] 4-01-00-01469 | |
| [Beilstein Reference] 4-02-00-01923 | |
| [EC Class] flammable, harmful, irritant | |
| [EC Class] harmful | |
| [Small spills/leaks] Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Use water spray to dilute spill to a non-flammable mixture. Avoid runoff into storm sewers and ditches which lead to waterways. Remove all sources of ignition. Use a spark-proof tool. Do not get water inside containers. A vapor suppressing foam may be used to reduce vapors. | |
| [Small spills/leaks] Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation. | |
| [Disposal Code] 13 | |
| [Disposal Code] 6 | |
| [Incompatibilities] Oxidizing agents, anhydrous hydrazine, moisture. | |
| [Stability] Stable under normal temperatures and pressures. | |
| [Stability] Stable under normal temperatures and pressures. Reacts with water to form toxic fumes. | |
| [Incompatibilities] Strong oxidizing agents, strong reducing agents, strong acids, strong bases. | |
| [Decomposition] Carbon monoxide, carbon dioxide, titanium/titanium oxides. | |
| [Decomposition] Nitrogen oxides, carbon monoxide, carbon dioxide, cyanide fumes. | |
| [Combustion Products] Fire may produce irritating, corrosive and/or toxic gases. | |
| [UN Number] 1993 | |
| [UN Number] 2811 | |
| [Hazard Class] 3 | |
| [Hazard Class] 6.1 | |
| [Packing Group] I; II; III | |
| [HS Code] 2905 19 00 | |
| [HS Code] 2926 90 95 |
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