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2-Butyne-1,4-diol

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[Flash Point]

152
[Autoignition]

410
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Combustible material; may burn but does not ignite readily. Extinguishing media: Do NOT get water inside containers. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
[Upper exp. limit]

35.7
[Lower exp. limit]

2.3
[Fire Potential]

May burn but does not ignite readily.
[Ingestion]

Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
[Inhalation]

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration.
[Skin]

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
[Eyes]

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
[Storage]

Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
[Handling]

Wash thoroughly after handling. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Use with adequate ventilation. Wash clothing before reuse.
[Inhalation]

Can produce delayed pulmonary edema. Causes respiratory tract irritation with possible burns.
[Skin]

May cause dermatitis. Causes severe skin irritation and possible burns.
[Eyes]

Causes eye irritation and possible burns. May cause chemical conjunctivitis.
[Ingestion]

Harmful if swallowed. Causes digestive tract irritation with possible burns.
[Hazards]

When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards. May polymerize explosively when heated or involved in a fire. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form.
[EC Risk Phrase]

R 21 23/25 34 48/22
[EC Safety Phrase]

S 26 36/37/39 45
[UN (DOT)]

2716
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear neoprene gloves, apron, and/or clothing. Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear neoprene gloves, apron, and/or clothing. Wear appropriate protective clothing to prevent skin exposure.
[Respirators]

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
[Exposure Effects]

Prolonged or repeated skin contact may cause dermatitis. Effects may be delayed.
[Poison Class]

3
[Appearance]

White to light-brown solid or brownish-yellow aqueous solution.
[Solubility in water]

Very soluble
[Melting Point]

55 - 58
[Boiling Point]

238
[Vapor Pressure]

0.008 (25 C)
[Density]

1.1001 g/cm3 (20 C)
[pKa/pKb]

12.72 (pKa)
[Partition Coefficient]

-1.1
[Heat Of Vaporization]

55.2 kJ/mol
[Heat Of Combustion]

-2204 kJ/mol
[Usage]

Intermediate, corrosion inhibitor, electroplating brightener, defoliant, polymerization accelerator, stabilizer for chlorinated hydrocarbons, cosolvent for paintermediate & varnish removal.
[Refractive Index]

1.4804 (20 C)
[Product Name]

BOZ
[Synonyms]

2-Butyne-1,4-diol
But-2-yne-1,4-diol
Butynediol
[CAS]

"CASEN_110-65-6.htm">110-65-6
[Formula]

C4H6O2
[Molecular Weight]

86.09
[EINECS]

203-788-6
[RTECS]

ES0525000
[RTECS Class]

Tumorigen; Reproductive Effector
[Beilstein/Gmelin]

1071237
[Beilstein Reference]

4-01-00-02687
[EC Index Number]

603-076-00-9
[EC Class]

Toxic; Harmful; Corrosive
[Small spills/leaks]

Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Remove all sources of ignition. Provide ventilation. Do not get water inside containers.
[Disposal Code]

9
[Stability]

Stable at room temperature in closed containers under normal storage and handling conditions.
[Incompatibilities]

Strong acids, strong bases.
[Decomposition]

Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
[Combustion Products]

Fire may produce irritating, corrosive and/or toxic gases.
[UN Number]

2716
[Hazard Class]

6.1
[Packing Group]

III
[HS Code]

2905 39 80