| [Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Extinguishing media: Do NOT get water inside containers. For small fires, use dry chemical, carbon dioxide, or water spray. For large fires, use dry chemical, carbon dioxide, alcohol-resistant foam, or water spray. Cool containers with flooding quantities of water until well after fire is out. | |
| [Fire Potential] Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. | |
| [Ingestion] Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. | |
| [Inhalation] Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. | |
| [Skin] Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes. | |
| [Eyes] Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes). | |
| [Storage] Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area. Store protected from moisture. | |
| [Handling] Use only in a well ventilated area. Minimize dust generation and accumulation. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Discard contaminated shoes. | |
| [Inhalation] May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract. Aspiration may lead to pulmonary edema. May cause systemic effects. | |
| [Skin] Causes skin burns. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color. | |
| [Eyes] Causes eye burns. May cause chemical conjunctivitis and corneal damage. | |
| [Ingestion] May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May cause perforation of the digestive tract. May cause systemic effects. | |
| [Hazards] Contact with metals may evolve flammable hydrogen gas. | |
| [UN (DOT)] 1759 | |
| [Personal Protection] Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. | |
| [Respirators] A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. | |
| [Exposure Effects] Effects may be delayed. | |
| [Appearance] Light yellow solid. | |
| [Solubility in water] Very soluble | |
| [Melting Point] 119 - 120 | |
| [Boiling Point] 110 (0.0001 torr) | |
| [pKa/pKb] 10.53 (pKb) | |
| [Usage] Prolongation of m intermediate lifetime in d96n mutant of bacteriorhodopsin. | |
| [Product Name] Cyclen | |
| [Synonyms] 1,4,7,10-Tetraazacyclododecane Cyclen | |
| [CAS] "CASEN_294-90-6.htm">294-90-6 | |
| [Formula] C8H20N4 | |
| [Molecular Weight] 172.27 | |
| [RTECS] XA5253000 | |
| [RTECS Class] Drug | |
| [Beilstein/Gmelin] 606114 | |
| [Beilstein Reference] 5-26-11-00023 | |
| [Small spills/leaks] Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation. | |
| [Incompatibilities] Moisture, strong acids, strong bases, strong oxidizing agents. | |
| [Stability] Stable at room temperature in closed containers under normal storage and handling conditions. | |
| [Decomposition] Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide. | |
| [Combustion Products] Fire may produce irritating, corrosive and/or toxic gases. | |
| [UN Number] 1759 | |
| [Hazard Class] 8 | |
| [Packing Group] I; II; III |
Print