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Dodecane

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[Flash Point]

71
[Autoignition]

200
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Water may be ineffective. Material is lighter than water and a fire may be spread by the use of water. Combustible Liquid. Extinguishing media: Use water spray to cool fire-exposed containers. Water may be ineffective. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
[Upper exp. limit]

4.7
[Lower exp. limit]

.6
[Fire Potential]

This chemical is combustible.
[Ingestion]

Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
[Inhalation]

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
[Skin]

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
[Eyes]

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
[Storage]

Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
[Handling]

Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
[Inhalation]

May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Aspiration may lead to pulmonary edema. Inhalation at high concentrations may cause CNS depression and asphixiation.
[Skin]

May cause irritation and dermatitis. May cause cyanosis of the extremities.
[Eyes]

May cause eye irritation. May cause chemical conjunctivitis and corneal damage.
[Ingestion]

May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
[Hazards]

Disaster hazard: Dangerous; keep away from heat and open flame.
[EC Risk Phrase]

R 65
[EC Safety Phrase]

S 24/25
[UN (DOT)]

3295
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
[Respirators]

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
[Exposure Effects]

Mild central nervous system depression or excitation may occur after ingestion or vapor inhalation. CNS effects can occur secondary to hydrocarbon pneumonitis and hypoxia, or from additives and contaminants (aniline, heavy metals, camphor, or pesticides). Some hydrocarbons are simple asphyxiants (e.G., Methane, ethane, propane gasses) which can produce CNS effects secondary to hypoxia. In a prospective study in Toronto, major congenital malformations were noted in 13 of 125 fetuses of mothers exposed to organic solvents during pregnancy.
[Poison Class]

-
[Appearance]

Colorless liquid with gasoline-like odor.
[Solubility in water]

Insoluble
[Melting Point]

-9.6
[Boiling Point]

216
[Vapor Pressure]

0.21 (25 C)
[Density]

0.7487 g/cm3 (20 C)
[Partition Coefficient]

7.13
[Heat Of Vaporization]

34.4 kJ/mol
[Usage]

As solvent, in organic synth, as distillation chaser, in jet fuel research.
[Saturation Concentration]

400 ppm (0.04%) at 20 C (calc.)
[Vapor Density]

5.9
[Odor threshold]

37 mg/m3
[Refractive Index]

1.4210 (20 C)
[Product Name]

Dodecane
[Synonyms]

Bihexyl
Dihexyl
[CAS]

"CASEN_112-40-3.htm">112-40-3
[Formula]

C12H26
[Molecular Weight]

170.34
[EINECS]

203-967-9
[RTECS]

JR2125000
[RTECS Class]

Tumorigen
[Beilstein/Gmelin]

1697175
[Beilstein Reference]

4-01-00-00498
[EC Class]

harmful
[Small spills/leaks]

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation.
[Disposal Code]

1
[Incompatibilities]

Oxidizing agents.
[Stability]

Stable under normal temperatures and pressures.
[Decomposition]

Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
[Combustion Products]

Fire may produce irritating, corrosive and/or toxic gases.
[UN Number]

3295
[Hazard Class]

3
[Packing Group]

I; II; III
[HS Code]

2901 10 90