| [Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Dusts at sufficient concentrations can form explosive mixtures with air. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam. | |
| [Ingestion] Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. | |
| [Inhalation] Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration. | |
| [Skin] Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. | |
| [Eyes] Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. | |
| [Storage] Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from light. | |
| [Handling] Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Use with adequate ventilation. Store protected from light. Wash clothing before reuse. | |
| [Inhalation] Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Can produce delayed pulmonary edema. | |
| [Skin] May cause skin irritation. Causes skin irritation. | |
| [Eyes] Causes eye irritation. May cause chemical conjunctivitis. | |
| [Ingestion] May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated. | |
| [EC Risk Phrase] R 36/37/38 | |
| [EC Safety Phrase] S 26 36 | |
| [Personal Protection] Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. | |
| [Respirators] A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. | |
| [Exposure Effects] Effects may be delayed. | |
| [Poison Class] 4 | |
| [Appearance] Pinkish white to grey crystalline powder. Solid. | |
| [Solubility in water] Very soluble | |
| [Melting Point] 285 | |
| [Boiling Point] 466 | |
| [pKa/pKb] 10.36 (pKb) | |
| [Partition Coefficient] -.02 | |
| [Usage] Production of azo dyes. | |
| [Product Name] 4-Amino-3-hydroxynaphthalene-1-sulphonic acid | |
| [Synonyms] 1-Amino-2-naphthol-4-sulfonic acid 1-Amino-4-sulfo-2-naphthol 2-Hydroxy-4-sulfo-1-naphthylamine 4-Amino-3-hydroxy-1-naphthalenesulfonic acid 4-Amino-3-hydroxynaphthalene-1-sulfonic acid | |
| [CAS] "CASEN_116-63-2.htm">116-63-2 | |
| [Formula] C10H9NO4S | |
| [Molecular Weight] 239.25 | |
| [EINECS] 204-147-3 | |
| [RTECS] QK1292000 | |
| [RTECS Class] Mutagen | |
| [Merck] 13,453 | |
| [Beilstein/Gmelin] 2697469 | |
| [Beilstein Reference] 4-14-00-02825 | |
| [Small spills/leaks] Vacuum or sweep up material and place into a suitable disposal container. Reduce airborne dust and prevent scattering by moistening with water. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation. | |
| [Disposal Code] 4 | |
| [Stability] Stable at room temperature in closed containers under normal storage and handling conditions. May discolor on exposure to light. | |
| [Decomposition] Nitrogen oxides, carbon monoxide, oxides of sulfur, irritating and toxic fumes and gases, carbon dioxide, nitrogen. | |
| [HS Code] 2922 21 00 |
Print