[Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam. | |
[Fire Potential] Combustible material: may burn but does not ignite readily. | |
[Ingestion] Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. | |
[Inhalation] Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration. | |
[Skin] Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. | |
[Eyes] Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. | |
[Storage] Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. | |
[Handling] Wash thoroughly after handling. Wash hands before eating. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. | |
[Inhalation] May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Inhalation of arsenic compounds may lead to irritation of the respiratory tract and leading to possible nasal perforation. Long-term exposure to arsenic compounds may produce impairment of peripheral circulation. | |
[Skin] May cause skin irritation. Exposure to arsenic compounds may produce hyperpigmentation of the skin and hyperkeratoses of plantar and palmar surfacesas well as both primary irritation and sensitization types. | |
[Eyes] May cause eye irritation. May cause chemical conjunctivitis and corneal damage. | |
[Ingestion] May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. Ingestion of arsenical compounds may cause burning of the lips, throat constriction, swallowing difficulties, severe abdominal pain, severe nausea, projectile vomiting, and profuse diarrhea. Ingestion of arsenic compounds can produce convulsions, coma, and possibly death within 24 hours. | |
[Hazards] Containers may explode when heated. | |
[EC Risk Phrase] R 23/25 50/53 | |
[EC Safety Phrase] S 20/21 28 45 60 61 | |
[UN (DOT)] 1557 | |
[Personal Protection] Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. | |
[Respirators] A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. | |
[Exposure Effects] May cause liver and kidney damage. Chronic exposure to arsenical dust may cause breath shortness, nausea, chest pains, and garlic odor. | |
[Appearance] Gray-beige crystalline powder. | |
[Solubility in water] Very soluble | |
[Melting Point] 160 | |
[pKa/pKb] 4.21 (pKa) | |
[Product Name] 2-Aminobenzenearsonic acid | |
[Synonyms] (2-Aminophenyl)arsonic acid (o-Aminophenyl)arsonic acid 2-Aminobenzenearsonic acid 2-Aminophenylarsonic acid 2-Arsanilic acid o-Aminobenzenearsonic acid | |
[CAS] "CASEN_2045-00-3.htm">2045-00-3 | |
[Formula] C6H8AsNO3 | |
[Molecular Weight] 217.05 | |
[EINECS] 218-064-5 | |
[Beilstein/Gmelin] 2937145 | |
[Beilstein Reference] 4-16-00-01189 | |
[Small spills/leaks] Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation. | |
[Incompatibilities] Oxidizing agents. | |
[Stability] Stable under normal temperatures and pressures. | |
[Decomposition] Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen, oxides of arsenic. | |
[Combustion Products] Fire may produce irritating, corrosive and/or toxic gases. | |
[UN Number] 1557 | |
[Hazard Class] 6.1 | |
[Packing Group] I; II; III |