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Tropine

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[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Containers may explode in the heat of a fire. Non-combustible, substance itself does not burn but may decompose upon heating to produce irritating, corrosive and/or toxic fumes. Runoff from fire control or dilution water may cause pollution. Extinguishing media: Use water spray to cool fire-exposed containers. Substance is noncombustible; use agent most appropriate to extinguish surrounding fire. Do NOT get water inside containers.
[Fire Potential]

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
[Ingestion]

Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
[Inhalation]

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
[Skin]

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
[Eyes]

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
[Storage]

Store in a tightly closed container. Refrigerator (approx 4 C). Store protected from moisture.
[Handling]

Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
[Ingestion]

May cause irritation of the digestive tract. May cause cardiac disturbances. The toxicological properties of this substance have not been fully investigated. May cause central nervous system depression.
[Inhalation]

May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. May cause cardiac abnormalities. Inhalation at high concentrations may cause CNS depression and asphixiation.
[Skin]

May cause skin irritation.
[Eyes]

May cause eye irritation.
[Hazards]

Contact with metals may evolve flammable hydrogen gas.
[EC Risk Phrase]

R 20/22
[EC Safety Phrase]

S 22 36/37 46
[UN (DOT)]

2811
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves and clothing to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
[Respirators]

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
[Appearance]

White powder and chunks.
[Melting Point]

63
[Boiling Point]

233
[Density]

1.0161 g/cm3 (100 C)
[pKa/pKb]

3.20 (pKb)
[Usage]

Used to dilate the pupil of the eye.
[Refractive Index]

1.4792 (99.8 C)
[Product Name]

Tropine
[Synonyms]

1aH,5aH-Tropan-3a-ol
2,3-Dihydro-3a-hydroxy-8-methylnortropidine
2,3-Dihydro-3a-hydroxytropidine
8-Azabicyclo[3.2.1]octan-3-ol, 8-methyl-, (3-endo)-
Tropanol
[CAS]

"CASEN_120-29-6.htm">120-29-6
[Formula]

C8H15NO
[Molecular Weight]

141.21
[EINECS]

204-384-2
[RTECS]

YM3875000
[RTECS Class]

Drug
[Merck]

12,9912
[Beilstein/Gmelin]

80188
[Beilstein Reference]

5-21-01-00219
[EC Class]

harmful
[Small spills/leaks]

Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation.
[Disposal Code]

3
[Incompatibilities]

Moisture, oxidizing agents.
[Stability]

Stable under normal temperatures and pressures.
[Decomposition]

Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen.
[Combustion Products]

Fire may produce irritating, corrosive and/or toxic gases.
[UN Number]

2811
[Hazard Class]

6.1
[Packing Group]

I; II; III
[HS Code]

2939 99 90