| [Flash Point] >110 | |
| [Fire Fighting] Extinguish using agent most appropriate for surrounding fire. | |
| [Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Runoff from fire control or dilution water may cause pollution. Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam. | |
| [Fire Potential] Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. | |
| [Ingestion] May cause gastrointestinal irritation with nausea, vomiting and diarrhea. | |
| [Ingestion] Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. | |
| [Ingestion] Seek medical assistance. | |
| [Inhalation] Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. | |
| [Inhalation] Move victim to fresh air. Apply artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult. | |
| [Inhalation] Causes respiratory tract irritation. Can produce delayed pulmonary edema. | |
| [Skin] Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. | |
| [Skin] Remove and isolate contaminated clothing and shoes. Immediately flush with running water for at least 20 minutes. For minor skin contact, avoid spreading material on unaffected skin. | |
| [Skin] May cause skin irritation. | |
| [Eyes] May cause eye irritation. May cause chemical conjunctivitis. | |
| [Eyes] Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. | |
| [Eyes] Immediately flush with running water for at least 20 minutes. | |
| [Storage] Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. | |
| [Handling] Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation. | |
| [Ingestion] See Inhalation. | |
| [Inhalation] TOXIC; inhalation, ingestion, or skin contact with material may cause severe injury or death. Effects of contact or inhalation may be delayed. | |
| [Skin] Contact with molten substance may cause severe burns to skin and eyes. See Inhalation. | |
| [Eyes] See Inhalation. | |
| [Hazards] Contact with metals may evolve flammable hydrogen gas. | |
| [EC Risk Phrase] R 34 | |
| [EC Safety Phrase] S 22 24/25 | |
| [EC Safety Phrase] S 26 36/37/39 45 | |
| [UN (DOT)] 3261 | |
| [Personal Protection] Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. | |
| [Personal Protection] Wear appropriate protective gloves, clothing and goggles. | |
| [Respirators] Wear positive pressure self-contained breathing apparatus (SCBA). | |
| [Respirators] Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. | |
| [Exposure Effects] Effects may be delayed. | |
| [Appearance] Off-white powder. | |
| [Melting Point] 160 | |
| [Melting Point] 64 | |
| [Boiling Point] 325 | |
| [Partition Coefficient] 1.78 | |
| [Product Name] 3-Nitrobenzenesulfonyl chloride | |
| [Synonyms] 1H-Benzotriazole, 5-chloro- 3-Nitrophenylsulfonyl chloride 5-Chloro-2H-benzotriazole 5-Chlorobenzotriazole m-Nitrophenylsulfonyl chloride | |
| [CAS] "CASEN_121-51-7.htm">121-51-7 | |
| [CAS] "CASEN_94-97-3.htm">94-97-3 | |
| [Formula] C6H4ClN3 | |
| [Formula] C6H4ClNO4S | |
| [Molecular Weight] 153.57 | |
| [Molecular Weight] 221.62 | |
| [EINECS] 202-378-4 | |
| [EINECS] 204-476-2 | |
| [Beilstein/Gmelin] 121517 | |
| [Beilstein/Gmelin] 746542 | |
| [Beilstein Reference] 4-11-00-00182 | |
| [Beilstein Reference] 4-26-00-00118 | |
| [Small spills/leaks] ELIMINATE all ignition sources. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. DO NOT GET WATER INSIDE CONTAINERS. | |
| [Small spills/leaks] Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation. | |
| [Incompatibilities] Oxidizing agents. | |
| [Stability] Stable at room temperature in closed containers under normal storage and handling conditions. | |
| [Decomposition] Hydrogen chloride, nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen. | |
| [Combustion Products] Fire may produce irritating, corrosive and/or toxic gases. | |
| [UN Number] 3261 |
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