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4-Nitrobenzoyl chloride

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[Flash Point]

122
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Substance is noncombustible. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Extinguishing media: Do NOT use water directly on fire. Do NOT get water inside containers. For small fires, use dry chemical, carbon dioxide, or water spray. For large fires, use dry chemical, carbon dioxide, alcohol-resistant foam, or water spray. Cool containers with flooding quantities of water until well after fire is out.
[Fire Potential]

Combustible material.
[Ingestion]

Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
[Inhalation]

Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
[Skin]

Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Discard contaminated clothing in a manner which limits further exposure. Destroy contaminated shoes.
[Eyes]

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).
[Storage]

Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area.
[Handling]

Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Use with adequate ventilation. Discard contaminated shoes.
[Ingestion]

May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns.
[Inhalation]

Causes chemical burns to the respiratory tract. Effects of inhalation may be delayed.
[Skin]

Causes severe skin irritation and burns. Effects of contact may be delayed.
[Eyes]

Causes severe eye irritation and burns.
[Hazards]

Flash point data are not available for this chemical, but
[EC Risk Phrase]

R 34
[EC Safety Phrase]

S 26 36/37/39 45
[UN (DOT)]

1759
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
[Respirators]

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
[Poison Class]

2 (Very strong toxins)
[Appearance]

Yellow needles or powder with a pungent odor.
[Solubility in water]

Insoluble
[Melting Point]

97 - 98
[Boiling Point]

278
[Vapor Pressure]

0.0044 (25 C)
[Partition Coefficient]

2.17
[Heat Of Vaporization]

51.6 kJ/mol
[Vapor Density]

6.4
[Product Name]

4-Nitrobenzoic acid chloride
[Synonyms]

4-Nitrobenzoic acid chloride
4-Nitrobenzoyl chloride
p-Nitrobenzoic acid chloride
[CAS]

"CASEN_122-04-3.htm">122-04-3
[Formula]

C7H4ClNO3
[Molecular Weight]

185.57
[EINECS]

204-517-4
[RTECS]

DM6651000
[RTECS Class]

Mutagen; Reproductive Effector
[Merck]

12,6687
[Beilstein/Gmelin]

473192
[Beilstein Reference]

4-09-00-01191
[EC Class]

corrosive
[Small spills/leaks]

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Provide ventilation.
[Disposal Code]

11
[Stability]

Stable under normal temperatures and pressures.
[Incompatibilities]

Water, oxidizing agents, strong bases, alcohols.
[Decomposition]

Hydrogen chloride, nitrogen oxides, phosgene, carbon monoxide, carbon dioxide, nitrogen.
[Combustion Products]

Fire may produce irritating, corrosive and/or toxic gases.
[UN Number]

1759
[Hazard Class]

8
[Packing Group]

I; II; III
[HS Code]

2916 39 00