| [Flash Point] 60 | |
| [Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. | |
| [Fire Potential] Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. | |
| [Ingestion] Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. | |
| [Inhalation] Get medical aid immediately. Remove from exposure to fresh air immediately. Do not use mouth-to-mouth respiration if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. | |
| [Skin] Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes. | |
| [Eyes] Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes). | |
| [Storage] Keep container closed when not in use. Corrosives area. Do not expose to air. Store under nitrogen. Store in a cool, dry area away from incompatible substances. | |
| [Handling] Keep container tightly closed. Avoid contact with heat, sparks and flame. Do not get on skin or in eyes. Do not ingest or inhale. Use with adequate ventilation. Store protected from air. Use and store under nitrogen. Use only in a chemical fume hood. Discard contaminated shoes. | |
| [Inhalation] Causes chemical burns to the respiratory tract. Aspiration may lead to pulmonary edema. May cause systemic effects. May cause nausea, headache, and vomiting. | |
| [Skin] Causes skin burns. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color. | |
| [Eyes] Causes eye burns. May cause chemical conjunctivitis and corneal damage. | |
| [Ingestion] May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May cause systemic effects. May cause nausea, headache, and vomiting. | |
| [Hazards] Contact with metals may evolve flammable hydrogen gas. | |
| [EC Risk Phrase] R 34 | |
| [EC Safety Phrase] S 26 36/37/39 45 | |
| [UN (DOT)] 1760 | |
| [Personal Protection] Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves and clothing to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. | |
| [Respirators] A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. | |
| [Exposure Effects] Effects may be delayed. | |
| [Appearance] Clear, colorless liquid. With a stench. | |
| [Solubility in water] Very soluble | |
| [Boiling Point] 169 | |
| [Vapor Pressure] 1.5 (25 C) | |
| [Density] 1.0882 g/cm3 (20 C) | |
| [pKa/pKb] 4.87 (pKb) | |
| [Partition Coefficient] .17 | |
| [Heat Of Vaporization] 40.6 kJ/mol | |
| [Vapor Density] 3.56 | |
| [Refractive Index] 1.5384 (20 C) | |
| [Product Name] Thiomorpholine | |
| [Synonyms] 1,4-Thiazane 1-Thia-4-azacyclohexane Parathiazan Tetrahydro-1,4-thiazine Thiamorpholine | |
| [CAS] "CASEN_123-90-0.htm">123-90-0 | |
| [Formula] C4H9NS | |
| [Molecular Weight] 103.18 | |
| [EINECS] 204-660-2 | |
| [Merck] 12,9435 | |
| [Beilstein/Gmelin] 102550 | |
| [Beilstein Reference] 4-27-00-00636 | |
| [Small spills/leaks] Clean up spills immediately, using the appropriate protective equipment. Cover with an activated carbon adsorbent and place into a closed container for disposal. Provide ventilation. Place under an inert atmosphere. | |
| [Stability] Stable under normal temperatures and pressures. Air sensitive Volatile in steam. | |
| [Incompatibilities] Strong oxidizing agents, strong bases, air. | |
| [Decomposition] Nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide. | |
| [Combustion Products] Fire may produce irritating, corrosive and/or toxic gases. | |
| [UN Number] 1760 | |
| [Hazard Class] 8 | |
| [Packing Group] I; II; III |
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