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Folpet

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[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use agent most appropriate to extinguish fire.
[Ingestion]

Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place individual on the left side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. If possible, do not leave individual unattended.
[Inhalation]

If symptoms develop, move individual away from exposure and into fresh air. If symptoms persist, seek medical attention. If breathing is difficult, administer oxygen. Keep person warm and quiet; seek immediate medical attention.
[Skin]

Remove contaminated clothing. Wash exposed area with soap and water. If symptoms persist, seek medical attention. Launder clothing before reuse.
[Eyes]

Irrigate exposed eyes with copious amounts of tepid water for at least 15 minutes. If irritation, pain, swelling, lacrimation, or photophobia persist, the patient should be seen in a health care facility.
[Storage]

Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.
[Handling]

All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.
[Inhalation]

Folpet is a respiratory tract irritant and can produce occupational asthma.
[Skin]

Irritant and allergic contact dermatitis have been reported with captan, folpet, and captafol.
[Eyes]

Folpet is an irritant of the eyes and mucous membranes.
[Ingestion]

Nausea, vomiting, and diarrhea may follow ingestion.
[Personal Protection]

Goggles or a face shield.
[Respirators]

Use NIOSH/MSHA approved respirator appropriate for exposure of concern.
[Exposure Effects]

The phthalimide fungicides contain the phthalimide moiety in common with phthalidomide, a known human teratogen. Captan has been teratogenic, fetotoxic, and/or embryotoxic in a variety of rodent species and caused stillbirths in dogs. Folpet was teratogenic in rabbits, chicks, and hamsters. Captafol has been embryo- or fetotoxic in experimental animals. <br>Captan, folpet, and captafol have all induced testicular degeneration in laboratory animals.
[Poison Class]

4
[Appearance]

White crystals.
[Solubility in water]

Insoluble
[Melting Point]

442 - 446
[Vapor Pressure]

<0.0001
[Density]

1.78 g/cm3 (25 C)
[Partition Coefficient]

2.85
[Usage]

Fungicide.
[Product Name]

Folpet
[Synonyms]

2-((Trichloromethyl)thio)-1H-isoindole-1,3(2H)-dione
2-(Trichloromethylsulfanyl)isoindole-1,3-dione
Acryptan
N-(Trichloromethylthio)phthalimide
Orthophaltan
[CAS]

"CASEN_133-07-3.htm">133-07-3
[Formula]

C9H4Cl3NO2S
[Molecular Weight]

296.56
[EINECS]

205-088-6
[RTECS]

TI5685000
[RTECS Class]

Agricultural Chemical and Pesticide; Tumorigen; Mutagen; Reproductive Effector
[Merck]

12,4255
[Beilstein/Gmelin]

193373
[Beilstein Reference]

5-21-11-00118
[EC Index Number]

613-045-00-1
[EC Class]

Carcinogenic Category 3; Harmful; Irritant; Sensitising; Dangerous for the Environment
[Small spills/leaks]

Evacuate area and ventilate. Wear protective equipment. If required, use an inert absrobent. Sweep up and place in an appropriate container for disposal. Wash contaminated surfaces.
[Incompatibilities]

Strong oxidizing agents.
[Stability]

Virtually non-volatile; stable when dry, but slowly hydrolyzes in water at ordinary temperature, rapidly @ high temperature or under alkaline conditions.
[Decomposition]

When heated to decomposition it emits very toxic fumes of hydrogen chloride, nitrogen oxides and sulfur oxides.