[Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use agent most appropriate to extinguish fire. | |
[Ingestion] Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place individual on the left side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. If possible, do not leave individual unattended. | |
[Inhalation] If symptoms develop, move individual away from exposure and into fresh air. If symptoms persist, seek medical attention. If breathing is difficult, administer oxygen. Keep person warm and quiet; seek immediate medical attention. | |
[Skin] Remove contaminated clothing. Wash exposed area with soap and water. If symptoms persist, seek medical attention. Launder clothing before reuse. | |
[Eyes] Irrigate exposed eyes with copious amounts of tepid water for at least 15 minutes. If irritation, pain, swelling, lacrimation, or photophobia persist, the patient should be seen in a health care facility. | |
[Storage] Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage. | |
[Handling] All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood. | |
[Inhalation] Folpet is a respiratory tract irritant and can produce occupational asthma. | |
[Skin] Irritant and allergic contact dermatitis have been reported with captan, folpet, and captafol. | |
[Eyes] Folpet is an irritant of the eyes and mucous membranes. | |
[Ingestion] Nausea, vomiting, and diarrhea may follow ingestion. | |
[Personal Protection] Goggles or a face shield. | |
[Respirators] Use NIOSH/MSHA approved respirator appropriate for exposure of concern. | |
[Exposure Effects] The phthalimide fungicides contain the phthalimide moiety in common with phthalidomide, a known human teratogen. Captan has been teratogenic, fetotoxic, and/or embryotoxic in a variety of rodent species and caused stillbirths in dogs. Folpet was teratogenic in rabbits, chicks, and hamsters. Captafol has been embryo- or fetotoxic in experimental animals. <br>Captan, folpet, and captafol have all induced testicular degeneration in laboratory animals. | |
[Poison Class] 4 | |
[Appearance] White crystals. | |
[Solubility in water] Insoluble | |
[Melting Point] 442 - 446 | |
[Vapor Pressure] <0.0001 | |
[Density] 1.78 g/cm3 (25 C) | |
[Partition Coefficient] 2.85 | |
[Usage] Fungicide. | |
[Product Name] Folpet | |
[Synonyms] 2-((Trichloromethyl)thio)-1H-isoindole-1,3(2H)-dione 2-(Trichloromethylsulfanyl)isoindole-1,3-dione Acryptan N-(Trichloromethylthio)phthalimide Orthophaltan | |
[CAS] "CASEN_133-07-3.htm">133-07-3 | |
[Formula] C9H4Cl3NO2S | |
[Molecular Weight] 296.56 | |
[EINECS] 205-088-6 | |
[RTECS] TI5685000 | |
[RTECS Class] Agricultural Chemical and Pesticide; Tumorigen; Mutagen; Reproductive Effector | |
[Merck] 12,4255 | |
[Beilstein/Gmelin] 193373 | |
[Beilstein Reference] 5-21-11-00118 | |
[EC Index Number] 613-045-00-1 | |
[EC Class] Carcinogenic Category 3; Harmful; Irritant; Sensitising; Dangerous for the Environment | |
[Small spills/leaks] Evacuate area and ventilate. Wear protective equipment. If required, use an inert absrobent. Sweep up and place in an appropriate container for disposal. Wash contaminated surfaces. | |
[Incompatibilities] Strong oxidizing agents. | |
[Stability] Virtually non-volatile; stable when dry, but slowly hydrolyzes in water at ordinary temperature, rapidly @ high temperature or under alkaline conditions. | |
[Decomposition] When heated to decomposition it emits very toxic fumes of hydrogen chloride, nitrogen oxides and sulfur oxides. |