| [Flash Point] 157 | |
| [Autoignition] 485 | |
| [Fire Fighting] Extinguish fire using agent suitable for type of surrounding fire. (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog. Use foam, dry chemical, or carbon dioxide. Keep run-off water out of sewers and water sources. | |
| [Fire Potential] Slightly flammable. | |
| [Ingestion] DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. | |
| [Inhalation] IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. IMMEDIATELY call a physician and be prepared to transport the victim to a hospital even if no symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used. | |
| [Skin] IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. IMMEDIATELY call a hospital or poison control center even if no symptoms (such as redness or irritation) develop. IMMEDIATELY transport the victim to a hospital for treatment after washing the affected areas. | |
| [Eyes] First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. | |
| [Storage] 1-Naphthylamine should be stored at cool ambiant temperatures. Irritating gases are produced when subjected to heat. | |
| [Handling] All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood. | |
| [Inhalation] Dyspnea and tachypnea may occur. | |
| [Skin] Central cyanosis unresponsive to oxygen therapy is classic. | |
| [Eyes] See Inhalation. | |
| [Ingestion] Nausea and vomiting may occur. | |
| [Hazards] When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards. | |
| [UN (DOT)] 2077 | |
| [Personal Protection] Wear appropriate protective gloves, clothing and goggles. | |
| [Respirators] Wear positive pressure self-contained breathing apparatus (SCBA). | |
| [Exposure Effects] CNS effects include headache, dizziness, altered mental status, confusion (lethargy progressing coma), seizures, syncope; occur secondary to CNS hypoxia, usually with levels > 20%. | |
| [Exposure limit(s)] NIOSH REL: Ca See Appendix A OSHA PEL: [1910.1004] See Appendix B | |
| [Appearance] A crystalline solid or a solid dissolved in a liquid. | |
| [Solubility in water] 20 mg/L | |
| [Melting Point] 50 | |
| [Boiling Point] 300 | |
| [Vapor Pressure] 0.0011 (25 C) | |
| [Density] 1.171 g/cm3 (20 C) | |
| [pKa/pKb] 1.06 (pKa) | |
| [Partition Coefficient] 168.49 | |
| [Heat Of Vaporization] 54.1 kJ/mol | |
| [Heat Of Combustion] -5316 kJ/mol | |
| [Usage] Toning prints made with cerium salts. | |
| [Vapor Density] 4.93 | |
| [Refractive Index] 1.6594 (51.2 C) | |
| [Product Name] Naphthalidam | |
| [Synonyms] 1-Aminonaphthalene alpha-Naphthylamine Naphthalen-1-amine Naphthalidine | |
| [CAS] "CASEN_134-32-7.htm">134-32-7 | |
| [Formula] C10H9N | |
| [Molecular Weight] 143.19 | |
| [EINECS] 205-138-7 | |
| [RTECS] QM1400000 | |
| [RTECS Class] Tumorigen; Mutagen | |
| [Merck] 12,6485 | |
| [Beilstein/Gmelin] 386133 | |
| [Beilstein Reference] 4-12-00-03009 | |
| [EC Index Number] 612-020-00-2 | |
| [EC Class] Harmful; Dangerous for the Environment | |
| [Small spills/leaks] Keep sparks, flames, and other sources of ignition away. Keep material out of water sources and sewers. Build dikes to contain flow as necessary. Do not use water. Land spill: Dig a pit, pond, lagoon, holding area to contain liquid or solid material. Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water. Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete. Water spill: Use natural barriers or oil spill control booms to limit spill travel. Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom. Remove trapped material with suction hoses. | |
| [Incompatibilities] Incompatible with oxidizing agents Incompatible with nitrous acid. | |
| [Stability] Oxidizes in air. | |
| [Combustion Products] Toxic nitrogen oxides are produced in a fire. | |
| [UN Number] 2077 | |
| [Hazard Class] 6.1 | |
| [Packing Group] III |
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