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Acetylenedicarboxylic acid

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[Flash Point]

131
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.
[Fire Potential]

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
[Ingestion]

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
[Inhalation]

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
[Skin]

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
[Eyes]

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
[Storage]

Store in a cool, dry place. Store in a tightly closed container. Refrigerator (approx 4 C).
[Handling]

Wash thoroughly after handling. Wash hands before eating. Use only in a well ventilated area. Minimize dust generation and accumulation. Do not get on skin or in eyes. Do not ingest or inhale.
[Ingestion]

Causes gastrointestinal irritation with nausea, vomiting and diarrhea.
[Inhalation]

May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema.
[Skin]

May cause severe irritation and possible burns.
[Eyes]

Contact with eyes may cause severe irritation, and possible eye burns.
[Hazards]

Contact with metals may evolve flammable hydrogen gas.
[EC Risk Phrase]

R 23/24/25 36/38
[EC Safety Phrase]

S 26 36/37/39 45
[UN (DOT)]

3261
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves and clothing to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
[Respirators]

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
[Appearance]

Light beige solid.
[Solubility in water]

Very soluble
[Melting Point]

180 - 185
[Boiling Point]

292
[pKa/pKb]

0.67 (pKa)
[Partition Coefficient]

-.26
[Product Name]

Acetylenedicarboxylic acid
[Synonyms]

2-Butyne-1,4-dioic acid
2-Butynedioic acid
Acetylenedicarboxylic acid
But-2-ynedioic acid
[CAS]

"CASEN_142-45-0.htm">142-45-0
[Formula]

C4H2O4
[Molecular Weight]

114.06
[EINECS]

205-536-0
[Beilstein/Gmelin]

878357
[Beilstein Reference]

4-02-00-02290
[Small spills/leaks]

Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal.
[Disposal Code]

4
[Incompatibilities]

Bases; reducing agents; and oxidizing agents.
[Stability]

Stable under normal temperatures and pressures.
[Decomposition]

Carbon monoxide, carbon dioxide.
[Combustion Products]

Fire may produce irritating, corrosive and/or toxic gases.
[UN Number]

3261
[Hazard Class]

8
[Packing Group]

I; II; III
[HS Code]

2917 19 90