| [Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam. | |
| [Ingestion] Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. | |
| [Inhalation] Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. | |
| [Skin] Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. | |
| [Eyes] Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. | |
| [Storage] Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Do not expose to air. Store protected from light. Store under an inert atmosphere. | |
| [Handling] Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Store protected from light. Handle under an inert atmosphere. Store protected from air. | |
| [Inhalation] Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Exposure to high concentrations of mercaptans can produce unconsciousness with cyanosis, cold extremities and rapid pulse. Mercaptans may cause nausea and headache. | |
| [Skin] Causes skin irritation. The toxicological properties of this material have not been fully investigated. | |
| [Eyes] Causes eye irritation. | |
| [Ingestion] Causes gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated. Mercaptans may cause nausea and headache. Exposure to high concentrations of mercaptans can produce unconsciousness with cyanosis, cold extremities and rapid pulse. | |
| [EC Risk Phrase] R 36/37/38 | |
| [EC Safety Phrase] S 22 26 36 | |
| [UN (DOT)] 3335 | |
| [Personal Protection] Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. | |
| [Respirators] Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. | |
| [Exposure Effects] Irritating to eyes, respiratory system and skin. | |
| [Appearance] Yellow powder. With a stench. | |
| [Solubility in water] Very soluble | |
| [Melting Point] 165 - 166 | |
| [Boiling Point] 230 (0.02 torr) | |
| [Density] 1.489 g/cm3 (20 C) | |
| [pKa/pKb] 3.50 (pKa) | |
| [Usage] Manufacture of thioindigo dyes, reagent for determination of iron. | |
| [Product Name] 2-Mercaptobenzoic acid | |
| [Synonyms] 2-Sulfanylbenzoic acid o-Thiosalicylic acid Thiophenol-2-carboxylic acid | |
| [CAS] "CASEN_147-93-3.htm">147-93-3 | |
| [Formula] C7H6O2S | |
| [Molecular Weight] 154.19 | |
| [EINECS] 205-704-3 | |
| [RTECS] DH3325000 | |
| [RTECS Class] Other | |
| [Merck] 12,9498 | |
| [Beilstein/Gmelin] 508507 | |
| [Beilstein Reference] 4-10-00-00272 | |
| [EC Class] irritant | |
| [Small spills/leaks] Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation. Place under an inert atmosphere. | |
| [Incompatibilities] Oxidizing agents. | |
| [Stability] Stable at room temperature in closed containers under normal storage and handling conditions. | |
| [Decomposition] Carbon monoxide, oxides of sulfur, irritating and toxic fumes and gases, carbon dioxide. | |
| [UN Number] 3335 | |
| [HS Code] 2930 90 70 |
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