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4-Pyrrolidinopyridine

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[Flash Point]

113
[Autoignition]

330
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Containers may explode when heated. Non-combustible, substance itself does not burn but may decompose upon heating to produce irritating, corrosive and/or toxic fumes. Runoff from fire control or dilution water may cause pollution. Extinguishing media: Use water spray to cool fire-exposed containers. Do NOT get water inside containers. For small fires, use dry chemical, carbon dioxide, or water spray. For large fires, use dry chemical, carbon dioxide, alcohol-resistant foam, or water spray.
[Fire Potential]

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
[Ingestion]

Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
[Inhalation]

Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
[Skin]

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
[Eyes]

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
[Storage]

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
[Handling]

Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
[Inhalation]

Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. May cause cardiac abnormalities. Inhalation at high concentrations may cause CNS depression and asphixiation.
[Skin]

Causes skin irritation.
[Eyes]

Causes eye irritation and possible injury.
[Ingestion]

May cause irritation of the digestive tract. May cause cardiac disturbances. The toxicological properties of this substance have not been fully investigated. May cause central nervous system depression.
[Hazards]

Contact with metals may evolve flammable hydrogen gas.
[EC Risk Phrase]

R 25 35
[EC Safety Phrase]

S 26 36/37/39 45
[UN (DOT)]

2811
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
[Respirators]

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
[Exposure Effects]

Effects may be delayed.
[Appearance]

Slightly brown crystals.
[Solubility in water]

Very soluble
[Melting Point]

55 - 56
[Boiling Point]

263
[Vapor Pressure]

0.01 (25 C)
[pKa/pKb]

3.89 (pKb)
[Partition Coefficient]

1.43
[Heat Of Vaporization]

50.1 kJ/mol
[Product Name]

4-(Pyrrolidin-1-yl)pyridine
[Synonyms]

4-(Pyrrolidin-1-yl)pyridine
4-Pyrrolidin-1-ylpyridine
Pyridine, 4-(1-pyrrolidinyl)-
[CAS]

"CASEN_2456-81-7.htm">2456-81-7
[Formula]

C9H12N2
[Molecular Weight]

148.21
[EINECS]

219-534-2
[Beilstein/Gmelin]

472443
[Beilstein Reference]

5-22-09-00122
[Small spills/leaks]

Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation.
[Disposal Code]

5
[Incompatibilities]

Acids, oxidizing agents.
[Stability]

Stable under normal temperatures and pressures.
[Decomposition]

Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen.
[Combustion Products]

Fire may produce irritating, corrosive and/or toxic gases.
[UN Number]

2811
[Hazard Class]

6.1
[Packing Group]

I; II; III
[HS Code]

2933 39 99