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2-Bromo-4'-methoxyacetophenone

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[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
[Fire Potential]

May burn but not readily ignited.
[Ingestion]

Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
[Inhalation]

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
[Skin]

Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
[Eyes]

Get medical aid immediately. Extensive irrigation is required (at least 30 minutes).
[Storage]

Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Refrigerator (approx 4 C). Keep containers tightly closed.
[Handling]

Use only in a well ventilated area. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
[Ingestion]

Causes gastrointestinal irritation with nausea, vomiting and diarrhea.
[Inhalation]

May cause respiratory difficulty and coughing. Causes respiratory tract irritation with possible burns.
[Skin]

Causes skin irritation.
[Eyes]

Produces irritation, characterized by a burning sensation, redness, tearing, inflammation, and possible corneal injury. Lachrymator.
[Hazards]

Containers may explode when heated.
[EC Risk Phrase]

R 36/37/38
[EC Safety Phrase]

S 26 36/37/39
[UN (DOT)]

1693
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
[Respirators]

Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions.
[Appearance]

Light brown powder.
[Solubility in water]

Insoluble
[Melting Point]

67 - 70
[Boiling Point]

285
[Partition Coefficient]

1.87
[Product Name]

2-Bromo-1-(4-methoxyphenyl)ethanone
[Synonyms]

2-(4-Methoxyphenyl)-2-oxoethyl bromid
2-Bromo-1-(4-methoxyphenyl)ethanone
2-Bromo-p-methoxyacetophenone
Bromomethyl p-anisyl ketone
p-Methoxyphenacyl bromide
[CAS]

"CASEN_2632-13-5.htm">2632-13-5
[Formula]

C9H9BrO2
[Molecular Weight]

229.08
[EINECS]

220-118-8
[Beilstein/Gmelin]

743112
[Beilstein Reference]

4-08-00-00351
[Small spills/leaks]

Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation. Use water spray to reduce vapors or divert vapor cloud drift.
[Disposal Code]

3
[Stability]

Stable under normal temperatures and pressures.
[Incompatibilities]

Strong oxidizing agents - strong bases.
[Decomposition]

Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen bromide.
[Combustion Products]

Fire will produce irritating, corrosive and/or toxic gases.
[UN Number]

1693
[Hazard Class]

6.1
[Packing Group]

II
[HS Code]

2914 70 90