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[(2-Chlorophenyl)methylene]malononitrile

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[Flash Point]

148
[Fire Fighting]

Fires involving this compound should be controlled with a dry chemical, carbon dioxide or Halon extinguisher.
[Fire Potential]

Combustible material: may burn but does not ignite readily.
[Ingestion]

DO NOT INDUCE VOMITING. Corrosive chemicals will destroy the membranes of the mouth, throat, and esophagus and, in addition, have a high risk of being aspirated into the victim's lungs during vomiting which increases the medical problems. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. IMMEDIATELY transport the victim to a hospital. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. Transport the victim IMMEDIATELY to a hospital.
[Inhalation]

IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used.
[Skin]

IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. IMMEDIATELY call a hospital or poison control center even if no symptoms (such as redness or irritation) develop. IMMEDIATELY transport the victim to a hospital for treatment after washing the affected areas.
[Eyes]

First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.
[Storage]

Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.
[Handling]

All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.
[Inhalation]

Cough, rhinorrhea, sneezing, chest tightness, and laryngospasm may occur shortly following exposure due to the irritant effects.
[Skin]

Contact with molten substance may cause severe burns to skin and eyes. See Inhalation.
[Eyes]

See Inhalation.
[Ingestion]

A metallic taste with a burning sensation of the tongue is common. Nausea is common; vomiting occurs occasionally. Epigastric discomfort and burping may occur if tear gas is swallowed.
[Hazards]

When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
[UN (DOT)]

2810
[Personal Protection]

Wear appropriate protective gloves, clothing and goggles.
[Respirators]

Wear positive pressure self-contained breathing apparatus (SCBA).
[Exposure Effects]

Agitation and syncope, both attributed to panic, have been reported.
[Exposure limit(s)]

NIOSH REL: C 0.05 ppm (0.4 mg/m3) [skin] OSHA PEL: TWA 0.05 ppm (0.4 mg/m3) IDLH 2 mg/m3
[Poison Class]

2
[Appearance]

White crystalline solid or light beige powder. Odor of pepper.
[Solubility in water]

Insoluble
[Melting Point]

95.2 - 95.8
[Boiling Point]

310
[Vapor Pressure]

0.0005 (25 C)
[Density]

1.389 g/cm3 (25 C)
[Partition Coefficient]

2.67
[Heat Of Vaporization]

55.4 kJ/mol
[Usage]

It is used primarily as an incapacitating agent, both by military & law enforcement personnel. It can be disseminated in burning grenades & weapon-fired projectiles, as an aerosol from the finely divided solid chemical, or from a solution of the chemical dissolved in methylene chloride or acetone.
[Product Name]

[(2-Chlorophenyl)methylene]malononitrile
[Synonyms]

[(2-Chlorophenyl)methylene]malononitrile
[(2-Chlorophenyl)methylene]propanedinitrile
Alonitrile
o-Chlorobenzalmalononitrile
[CAS]

"CASEN_2698-41-1.htm">2698-41-1
[Formula]

C10H5ClN2
[Molecular Weight]

188.62
[EINECS]

220-278-9
[RTECS]

OO3675000
[RTECS Class]

Tumorigen; Mutagen; Reproductive Effector; Human Data; Primary Irritant
[Merck]

12,2178
[Beilstein/Gmelin]

1866635
[Beilstein Reference]

2-09-00-00641
[Small spills/leaks]

If a spill of this chemical occurs, FIRST REMOVE ALL SOURCES OF IGNITION, then you should dampen the solid spill material with acetone and transfer the dampened material to a suitable container. Use absorbent paper dampened with acetone to pick up any remaining material. Seal your contaminated clothing and the absorbent paper in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with acetone followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.
[Incompatibilities]

May react with strong oxidizers.
[Stability]

No data.
[Decomposition]

When heated to decomposition it emits very toxic fumes of hydrogen chloride, nitrogen oxides and cyanides.
[Combustion Products]

Fire may produce irritating, corrosive and/or toxic gases.
[UN Number]

2810
[Hazard Class]

6.1
[Packing Group]

I; II; III