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Methyl 3-chlorobenzoate

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[Flash Point]

104
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
[Ingestion]

Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
[Inhalation]

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration.
[Skin]

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
[Eyes]

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
[Storage]

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
[Handling]

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. Use with adequate ventilation.
[Inhalation]

Causes respiratory tract irritation. Can produce delayed pulmonary edema.
[Skin]

Causes skin irritation.
[Eyes]

Causes eye irritation. May cause chemical conjunctivitis.
[Ingestion]

May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
[EC Safety Phrase]

S 24/25
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
[Respirators]

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
[Exposure Effects]

Effects may be delayed.
[Appearance]

Clear, light yellow liquid.
[Solubility in water]

Insoluble
[Melting Point]

21
[Boiling Point]

231
[Vapor Pressure]

0.06 (25 C)
[Density]

1.23 g/cm3 (20 C)
[Partition Coefficient]

2.99
[Heat Of Vaporization]

46.8 kJ/mol
[Refractive Index]

1.53 (20 C)
[Product Name]

3-Chlorobenzoic acid methyl ester
[Synonyms]

Benzoic acid, 3-chloro-, methyl este
Methyl m-chlorobenzoate
[CAS]

"CASEN_2905-65-9.htm">2905-65-9
[Formula]

C8H7ClO2
[Molecular Weight]

170.6
[EINECS]

220-814-1
[Merck]

13,2142
[Beilstein/Gmelin]

2045126
[Beilstein Reference]

3-09-00-01346
[Small spills/leaks]

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Provide ventilation.
[Stability]

Stable at room temperature in closed containers under normal storage and handling conditions.
[Incompatibilities]

Strong oxidizing agents.
[Decomposition]

Hydrogen chloride, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
[Combustion Products]

During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.