| [Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. This material in sufficient quantity and reduced particle size is capable of creating a dust explosion. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use agent most appropriate to extinguish fire. | |
| [Ingestion] If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. | |
| [Inhalation] Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. | |
| [Skin] Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. | |
| [Eyes] Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. | |
| [Storage] Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. | |
| [Handling] Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. | |
| [Inhalation] May cause respiratory tract irritation. | |
| [Skin] May cause skin irritation. | |
| [Eyes] Causes eye irritation. | |
| [Ingestion] May cause irritation of the digestive tract. | |
| [EC Risk Phrase] R 36 51/53 | |
| [EC Safety Phrase] S 26 61 | |
| [UN (DOT)] 3077 | |
| [Personal Protection] Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. | |
| [Respirators] A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. | |
| [Exposure Effects] Prolonged or repeated skin contact may cause dermatitis. | |
| [Appearance] Black powder. | |
| [Solubility in water] Slightly soluble | |
| [Usage] To dye wool from an acid bath reddish-black, which can be converted to blue-black by afterchroming. | |
| [Product Name] C.I. 14645 | |
| [Synonyms] 1-Naphthalenesulfonic acid, 3-Hydroxy-4-((1-hydroxy-2-naphthalenyl)azo)-7-nitro-, monosodium salt 3-Hydroxy-4-(1-hydroxy-2-naphthlyazo)-7-nitro-1-naphthalene sulfonic acid, sodium salt C.I. 14645 Mordant black 11 Potting Black C Solochrome Black | |
| [CAS] "CASEN_1787-61-7.htm">1787-61-7 | |
| [Formula] C20H12N3NaO7S | |
| [Molecular Weight] 461.38 | |
| [EINECS] 217-250-3 | |
| [RTECS] QK2197000 | |
| [RTECS Class] Other | |
| [Merck] 12,3709 | |
| [Beilstein/Gmelin] 4121162 | |
| [EC Class] irritant, dangerous for the environment | |
| [Small spills/leaks] Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation. | |
| [Disposal Code] 3 | |
| [Stability] Stable under normal temperatures and pressures. | |
| [Incompatibilities] Strong oxidizing agents. | |
| [Decomposition] Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, sulfur oxides (SOx), including sulfur oxide and sulfur dioxide. | |
| [UN Number] 3077 | |
| [HS Code] 3204 19 00 |
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