| [Flash Point] 18 | |
| [Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Extinguishing media: Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water. In case of fire, use carbon dioxide, dry chemical powder or appropriate foam. | |
| [Fire Potential] HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. | |
| [Ingestion] Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. | |
| [Inhalation] Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. | |
| [Skin] Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. | |
| [Eyes] Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. | |
| [Storage] Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a cool, dry, well-ventilated area away from incompatible substances. Refrigerator/flammables. Keep containers tightly closed. | |
| [Handling] Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Use only in a chemical fume hood. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Do not breathe vapors. | |
| [Ingestion] May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Ingestion of large amounts may cause CNS depression. | |
| [Inhalation] Aspiration may lead to pulmonary edema. Vapors may cause dizziness or suffocation. May cause burning sensation in the chest. | |
| [Skin] May cause irritation and dermatitis. May cause cyanosis of the extremities. | |
| [Eyes] May cause eye irritation. May cause chemical conjunctivitis and corneal damage. | |
| [Hazards] Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. | |
| [EC Risk Phrase] R 11 36/37/38 | |
| [EC Safety Phrase] S 16 23 26 36 | |
| [UN (DOT)] 1993 | |
| [Personal Protection] Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. | |
| [Respirators] A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. | |
| [Appearance] Clear, colorless liquid. | |
| [Solubility in water] Slightly soluble | |
| [Boiling Point] 91 | |
| [Density] 0.8767 g/cm3 (20 C) | |
| [Vapor Density] 3.04 | |
| [Refractive Index] 1.4700 (20 C) | |
| [Product Name] Allyl methyl sulfide | |
| [Synonyms] 1-Propene, 3-(methylthio)- 2-Propenyl methyl sulfide 3-(Methylthio)propene Allyl methyl thioether Methyl 2-propenyl sulfide Methyl allyl sulfide | |
| [CAS] "CASEN_10152-76-8.htm">10152-76-8 | |
| [Formula] C4H8S | |
| [Molecular Weight] 88.16 | |
| [EINECS] 233-422-0 | |
| [Beilstein/Gmelin] 1735940 | |
| [Beilstein Reference] 4-01-00-02095 | |
| [Small spills/leaks] Wash area with soap and water. Clean up spills immediately, using the appropriate protective equipment. Cover with an activated carbon adsorbent and place into a closed container for disposal. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors. | |
| [Stability] Stable under normal temperatures and pressures. | |
| [Incompatibilities] Strong oxidizing agents, strong bases. | |
| [Decomposition] Carbon monoxide, oxides of sulfur, carbon dioxide, hydrogen sulfide. | |
| [Combustion Products] Fire may produce irritating, corrosive and/or toxic gases. | |
| [UN Number] 1993 | |
| [Hazard Class] 3 | |
| [Packing Group] I; II; III |
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