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Methyl 3-aminocrotonate

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[Flash Point]

91
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
[Ingestion]

Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
[Inhalation]

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
[Skin]

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
[Eyes]

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
[Storage]

Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep containers tightly closed.
[Handling]

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Avoid contact with skin and eyes. Keep container tightly closed. Avoid ingestion and inhalation. Wash clothing before reuse.
[Ingestion]

Causes gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
[Inhalation]

Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
[Skin]

Causes skin irritation.
[Eyes]

Causes eye irritation.
[EC Risk Phrase]

R 22 36
[EC Safety Phrase]

S 26 36/37/39
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate clothing to prevent skin exposure.
[Respirators]

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
[Poison Class]

4
[Appearance]

White crystalline powder.
[Solubility in water]

Very soluble
[Melting Point]

83 - 84
[Boiling Point]

194
[Vapor Pressure]

0.45 (25 C)
[pKa/pKb]

7.74 (pKb)
[Partition Coefficient]

-.14
[Heat Of Vaporization]

43.0 kJ/mol
[Vapor Density]

4
[Product Name]

Methyl 3-aminocrotonate
[Synonyms]

3-Aminocrotonic acid methyl ester
beta-Aminocrotonic acid methyl ester
Crotonic acid, 3-amino-, methyl ester
Methyl 3-amino-2-butenoate
Methyl 3-aminobut-2-enoate
Methyl beta-aminocrotonate
[CAS]

"CASEN_14205-39-1.htm">14205-39-1
[Formula]

C5H9NO2
[Molecular Weight]

115.13
[EINECS]

238-056-5
[RTECS]

EM9092500
[RTECS Class]

Primary Irritant
[Beilstein/Gmelin]

956592
[Beilstein Reference]

2-03-00-00414
[Small spills/leaks]

Clean up spills immediately, using the appropriate protective equipment. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions. Provide ventilation.
[Disposal Code]

3
[Stability]

Stable at room temperature in closed containers under normal storage and handling conditions.
[Incompatibilities]

Strong oxidizing agents.
[Decomposition]

Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
[HS Code]

2922 49 95