| [Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire use water spray, dry chemical, carbon dioxide, or appropriate foam. | |
| [Fire Potential] Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. | |
| [Ingestion] Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. | |
| [Inhalation] Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration. | |
| [Skin] Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes. | |
| [Eyes] Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes). | |
| [Storage] Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area. Keep containers tightly closed. | |
| [Handling] Wash thoroughly after handling. Wash hands before eating. Use only in a well ventilated area. Avoid contact with skin and eyes. Keep container tightly closed. Avoid ingestion and inhalation. Wash clothing before reuse. Discard contaminated shoes. | |
| [Ingestion] May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. | |
| [Inhalation] May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract. | |
| [Skin] Causes skin burns. | |
| [Eyes] Causes eye burns. | |
| [Hazards] Contact with metals may evolve flammable hydrogen gas. | |
| [EC Risk Phrase] R 36/38 | |
| [EC Safety Phrase] S 22 26 36 | |
| [UN (DOT)] 1759 | |
| [Personal Protection] Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. | |
| [Respirators] A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. | |
| [Appearance] Dark rust crystalline powder. | |
| [Solubility in water] Insoluble | |
| [Melting Point] 157 | |
| [Density] 1.363 g/cm3 (20 C) | |
| [Usage] Homogeneous hydrogenation catalyst. | |
| [Vapor Density] 31.9 | |
| [Product Name] Chlorotris(triphenylphosphine)rhodium(I) | |
| [Synonyms] Chlorotris(triphenylphosphine)rhodium | |
| [CAS] "CASEN_14694-95-2.htm">14694-95-2 | |
| [Formula] C54H45ClP3Rh | |
| [Molecular Weight] 925.24 | |
| [EINECS] 238-744-5 | |
| [Merck] 12,2226 | |
| [Beilstein/Gmelin] 4581440 | |
| [EC Class] irritant | |
| [Small spills/leaks] Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation. | |
| [Disposal Code] 27 | |
| [Stability] Stable at room temperature in closed containers under normal storage and handling conditions. | |
| [Incompatibilities] Strong oxidizing agents. | |
| [Decomposition] Hydrogen chloride, carbon monoxide, oxides of phosphorus, carbon dioxide. | |
| [Combustion Products] Fire may produce irritating, corrosive and/or toxic gases. | |
| [UN Number] 1759 | |
| [Hazard Class] 8 | |
| [Packing Group] I; II; III | |
| [HS Code] 2843 90 90 |
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