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3-Aminothiophenol

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[Flash Point]

79
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use water spray to keep fire-exposed containers cool. Combustible Liquid. Containers may explode when heated. Extinguishing media: Use water spray to cool fire-exposed containers. Do NOT use straight streams of water. For small fires, use dry chemical, carbon dioxide, or water spray. For large fires, use water spray, fog or regular foam. Cool containers with flooding quantities of water until well after fire is out.
[Fire Potential]

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
[Ingestion]

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
[Inhalation]

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
[Skin]

Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
[Eyes]

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
[Storage]

Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
[Handling]

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
[Ingestion]

The toxicological properties of this substance have not been fully investigated.
[Inhalation]

The toxicological properties of this substance have not been fully investigated.
[Skin]

No information regarding skin irritation and other potential effects was found.
[Eyes]

No information regarding eye irritation and other potential effects was found.
[Hazards]

Contact with metals may evolve flammable hydrogen gas.
[UN (DOT)]

1760
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
[Respirators]

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
[Appearance]

Pale-yellow liquid.
[Solubility in water]

Soluble
[Boiling Point]

110 - 112 (1 torr)
[Density]

1.1859 g/cm3 (20 C)
[pKa/pKb]

6.79 (pKa)
[Refractive Index]

1.6572 (20 C)
[Product Name]

3-Aminothiophenol
[Synonyms]

3-Aminothiophenol
3-Mercaptoaniline
m-Aminobenzenethiol
m-Aminothiophenol
[CAS]

"CASEN_22948-02-3.htm">22948-02-3
[Formula]

C6H7NS
[Molecular Weight]

125.18
[EINECS]

245-344-4
[Beilstein/Gmelin]

2074620
[Beilstein Reference]

1-13-00-00140
[Small spills/leaks]

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Remove all sources of ignition.
[Incompatibilities]

Acids, acid chlorides, acid anhydrides, chloroformates, strong oxidizing agents.
[Stability]

Stable under normal temperatures and pressures.
[Decomposition]

Nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide.
[Combustion Products]

Fire may produce irritating, corrosive and/or toxic gases.
[UN Number]

1760
[Hazard Class]

8
[Packing Group]

I; II; III