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Pyridine sulfur trioxide

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[Autoignition]

> 350
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire, use water spray, dry chemical, carbon dioxide, or alcohol-resistant foam.
[Ingestion]

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
[Inhalation]

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
[Skin]

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
[Eyes]

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
[Storage]

Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from water.
[Handling]

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
[Ingestion]

May be harmful if swallowed. Causes digestive tract irritation.
[Inhalation]

Causes respiratory tract irritation. Causes irritation of mucous membrane.
[Skin]

Causes mild skin irritation.
[Eyes]

Causes severe eye irritation.
[EC Risk Phrase]

R 22 34
[EC Safety Phrase]

S 26 36/37/39 45
[UN (DOT)]

3261
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
[Respirators]

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
[Appearance]

White to beige powder.
[Solubility in water]

Decomposition
[Melting Point]

155 - 165
[Usage]

Used as an activating electrophile in a swern like oxidation.
[Product Name]

Pyridine sulfur trioxide
[Synonyms]

Pyridine, compound with sulfur trioxide (1:1)
[CAS]

"CASEN_26412-87-3.htm">26412-87-3
[Formula]

C5H5NO3S
[Molecular Weight]

159.16
[EINECS]

247-683-3
[Beilstein/Gmelin]

3704116
[Beilstein Reference]

5-20-05-00184
[EC Class]

harmful, irritant
[Small spills/leaks]

Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal.
[Disposal Code]

12
[Incompatibilities]

Metals, strong oxidizing agents, moisture, diphenylmercury.
[Stability]

Stable under normal temperatures and pressures.
[Decomposition]

Nitrogen oxides, carbon monoxide, oxides of sulfur, irritating and toxic fumes and gases, carbon dioxide, nitrogen.
[UN Number]

3261
[HS Code]

2942 00 00