| [Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Do NOT use water directly on fire. Use foam, dry chemical, or carbon dioxide. | |
| [Fire Potential] Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. | |
| [Ingestion] Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. | |
| [Inhalation] Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. | |
| [Skin] Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes. | |
| [Eyes] Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes). | |
| [Storage] Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area. Keep containers tightly closed. | |
| [Handling] Wash thoroughly after handling. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Use with adequate ventilation. Discard contaminated shoes. | |
| [Ingestion] May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. | |
| [Inhalation] May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract. | |
| [Skin] Causes skin burns. | |
| [Eyes] Causes eye burns. Contact with eyes may cause severe irritation, and possible eye burns. | |
| [Hazards] Contact with metals may evolve flammable hydrogen gas. | |
| [EC Risk Phrase] R 25 34 | |
| [EC Safety Phrase] S 26 36/37/39 45 | |
| [UN (DOT)] 1759 | |
| [Personal Protection] Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. | |
| [Respirators] Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. | |
| [Appearance] White needles. | |
| [Solubility in water] Insoluble | |
| [Melting Point] 91 - 92 | |
| [Boiling Point] 80 - 85 (0.3 torr) | |
| [Usage] Toxic chemical warfare agent. | |
| [Product Name] Benzenemethanesulfonyl fluoride | |
| [Synonyms] Benzenemethanesulfonyl fluoride Benzylsulfonyl fluoride Phenylmethanesulfonyl fluoride Phenylmethylsulfonyl fluoride PMSF | |
| [CAS] "CASEN_329-98-6.htm">329-98-6 | |
| [Formula] C7H7FO2S | |
| [Molecular Weight] 174.18 | |
| [EINECS] 206-350-2 | |
| [RTECS] XT8040000 | |
| [RTECS Class] Other | |
| [Beilstein/Gmelin] 2088311 | |
| [Beilstein Reference] 3-11-00-00331 | |
| [Small spills/leaks] Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Provide ventilation. | |
| [Stability] Stable under normal temperatures and pressures. | |
| [Incompatibilities] Strong oxidizing agents, strong bases, moisture. | |
| [Decomposition] Carbon monoxide, oxides of sulfur, carbon dioxide, hydrogen fluoride. | |
| [Combustion Products] Fire may produce irritating, corrosive and/or toxic gases. | |
| [UN Number] 1759 | |
| [Hazard Class] 8 | |
| [Packing Group] I; II; III |
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