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4-Fluoroaniline

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[Flash Point]

74
[Autoignition]

>600
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire. Combustible Liquid. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.
[Fire Potential]

Combustible material: may burn but does not ignite readily.
[Ingestion]

Get medical aid. Wash mouth out with water.
[Inhalation]

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
[Skin]

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
[Eyes]

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
[Storage]

Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container. Keep from contact with oxidizing materials.
[Handling]

Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood.
[Inhalation]

May cause respiratory tract irritation. May be harmful if inhaled.
[Skin]

Causes skin irritation. May be harmful if absorbed through the skin.
[Eyes]

Causes eye irritation.
[Ingestion]

Harmful if swallowed. May cause irritation of the digestive tract.
[Hazards]

When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
[EC Risk Phrase]

R 20/21/22 36/38
[EC Safety Phrase]

S 26 36/37/39
[UN (DOT)]

2941
[Personal Protection]

Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
[Respirators]

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
[Exposure Effects]

Absorption into the body leads to the formation of methemoglobin which in sufficient concentrations causes cyanosis.
[Appearance]

Liquid.
[Solubility in water]

33 g/L
[Melting Point]

-1
[Boiling Point]

187
[Vapor Pressure]

0.6 (25 C)
[Density]

1.1613 g/cm3 (17 C)
[pKa/pKb]

9.34 (pKb)
[Partition Coefficient]

1.15
[Heat Of Vaporization]

42.5 kJ/mol
[Heat Of Combustion]

-3262 kJ/mol
[Usage]

Intermediate in manufacture of herbicides & plant growth regulators.
[Refractive Index]

1.5359 (17 C)
[Product Name]

4-Fluorobenzenamine
[Synonyms]

4-Fluoroaniline
4-Fluorobenzenamine
[CAS]

"CASEN_371-40-4.htm">371-40-4
[Formula]

C6H6FN
[Molecular Weight]

111.12
[EINECS]

206-735-5
[RTECS]

BY1575000
[RTECS Class]

Mutagen; Primary Irritant
[Merck]

13,4196
[Beilstein/Gmelin]

742030
[Beilstein Reference]

4-12-00-01104
[EC Class]

harmful, irritant
[Small spills/leaks]

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container.
[Disposal Code]

2
[Incompatibilities]

Acids, acid chlorides, strong oxidizing agents, acid anhydrides, chloroformates.
[Stability]

No data.
[Decomposition]

Nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen fluoride.
[Combustion Products]

Fire may produce irritating, corrosive and/or toxic gases.
[UN Number]

2941
[Hazard Class]

6.1
[Packing Group]

III
[HS Code]

2921 42 10