| [Flash Point] 54 | |
| [Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Extinguishing media: Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam. | |
| [Fire Potential] HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. | |
| [Ingestion] Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. | |
| [Inhalation] Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. | |
| [Skin] Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. | |
| [Eyes] Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. | |
| [Storage] Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area. Do not expose to air. Store under an inert atmosphere. | |
| [Handling] Use only in a well ventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Store protected from air. Use and store under nitrogen. Use only in a chemical fume hood. Wash clothing before reuse. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. | |
| [Inhalation] Causes respiratory tract irritation. Aspiration may lead to pulmonary edema. Vapors may cause dizziness or suffocation. May cause burning sensation in the chest. May cause headache, nausea and vomiting. | |
| [Skin] Causes skin irritation. May cause cyanosis of the extremities. | |
| [Eyes] Causes eye irritation. May cause chemical conjunctivitis and corneal damage. | |
| [Ingestion] May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Ingestion of large amounts may cause CNS depression. May cause headache and dizziness. | |
| [Hazards] Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. | |
| [EC Risk Phrase] R 10 20/21/22 36/37/38 | |
| [EC Safety Phrase] S 23 26 36/37/39 | |
| [UN (DOT)] 1993 | |
| [Personal Protection] Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. | |
| [Respirators] A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. | |
| [Exposure Effects] Effects may be delayed. | |
| [Appearance] Clear, colorless liquid. With a stench. | |
| [Solubility in water] Slightly soluble | |
| [Boiling Point] 164 | |
| [Density] 1.1996 g/cm3 (20 C) | |
| [pKa/pKb] 6.40 (pKa) | |
| [Vapor Density] 4.42 | |
| [Refractive Index] 1.5480 (20 C) | |
| [Product Name] 4-Mercaptofluorobenzene | |
| [Synonyms] (4-Fluorophenyl)thiol 4-Fluorobenzenethiol 4-Fluorophenyl mercaptan p-Fluorobenzenethiol p-Fluorothiophenol | |
| [CAS] "CASEN_371-42-6.htm">371-42-6 | |
| [Formula] C6H5FS | |
| [Molecular Weight] 128.16999999999999 | |
| [EINECS] 206-737-6 | |
| [Beilstein/Gmelin] 1446350 | |
| [Beilstein Reference] 4-06-00-01567 | |
| [EC Class] flammable, irritant | |
| [Small spills/leaks] Cover with an activated carbon adsorbent and place into a closed container for disposal. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. Place under an inert atmosphere. A vapor suppressing foam may be used to reduce vapors. | |
| [Incompatibilities] Air, strong bases, strong oxidizing agents. | |
| [Stability] Stable at room temperature in closed containers under normal storage and handling conditions. Air sensitive | |
| [Decomposition] Carbon monoxide, oxides of sulfur, carbon dioxide, hydrogen fluoride, hydrogen sulfide. | |
| [Combustion Products] Fire may produce irritating, corrosive and/or toxic gases. | |
| [UN Number] 1993 | |
| [Hazard Class] 3 | |
| [Packing Group] I; II; III | |
| [HS Code] 2930 90 70 |
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