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Methanesulfonamide

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[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use extinguishing media most appropriate for the surrounding fire.
[Ingestion]

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
[Inhalation]

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
[Skin]

Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
[Eyes]

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
[Storage]

Store in a cool, dry place. Store in a tightly closed container.
[Handling]

Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
[Ingestion]

May cause irritation of the digestive tract.
[Inhalation]

Causes respiratory tract irritation.
[Skin]

Causes skin irritation.
[Eyes]

Causes eye irritation.
[EC Risk Phrase]

R 36/37/38
[EC Safety Phrase]

S 26 36
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
[Respirators]

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
[Appearance]

Brown crystals.
[Solubility in water]

Very soluble
[Melting Point]

91 - 92
[Boiling Point]

180
[Density]

1 g/cm3
[pKa/pKb]

10.87 (pKa)
[Partition Coefficient]

-1.41
[Product Name]

Methanesulfonamide
[Synonyms]

Mesylamide
Methanesulfonic amide
[CAS]

"CASEN_3144-09-0.htm">3144-09-0
[Formula]

CH5NO2S
[Molecular Weight]

95.12
[EINECS]

221-553-6
[Beilstein/Gmelin]

1740835
[Beilstein Reference]

4-04-00-00028
[EC Class]

irritant
[Small spills/leaks]

Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions.
[Stability]

Stable under normal temperatures and pressures.
[Incompatibilities]

Strong oxidizing agents.
[Decomposition]

Carbon monoxide, oxides of nitrogen, oxides of sulfur, carbon dioxide.
[HS Code]

2935 00 90