| [Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam. | |
| [Ingestion] Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. | |
| [Inhalation] Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. | |
| [Skin] Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. | |
| [Eyes] Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. | |
| [Storage] Store in a cool, dry, well-ventilated area away from incompatible substances. Keep containers tightly closed. | |
| [Handling] Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale. Keep from contact with moist air and steam. Do not breathe dust. | |
| [Inhalation] May cause allergic respiratory reaction. Inhalation of high concentrations may cause coughing and shortness of breath. Can produce delayed pulmonary edema. | |
| [Skin] May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. May cause severe dermatitis and urticaria(hives). | |
| [Eyes] May cause eye irritation. | |
| [Ingestion] May cause irritation of the digestive tract. May cause central nervous system effects. | |
| [EC Risk Phrase] R 45 20/21/22 43 | |
| [EC Safety Phrase] S 53 45 | |
| [UN (DOT)] 3282 | |
| [Personal Protection] Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. | |
| [Respirators] A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. | |
| [Exposure Effects] May cause cancer according to animal studies. Prolonged or repeated exposure may cause lung irritation, chest pain, and pulmonary edema. May cause reproductive effects. | |
| [Exposure limit(s)] 0.1 mg/m3 TLV | |
| [Poison Class] 2 | |
| [Appearance] Light green solid. | |
| [Solubility in water] 4.8 g/L (20 C) | |
| [Boiling Point] 220 | |
| [Vapor Pressure] 20 (110 C) | |
| [Density] 1.455 g/cm3 (20 C) | |
| [Usage] This material is used as a catalyst. | |
| [Product Name] Bis(2,4-pentanediono)nickel | |
| [Synonyms] Bis(2,4-pentanedionato)nickel Bis(acetylacetonate)nickel Nickel bis(2,4-pentanedionate) Nickel bis(acetylacetonate) Nickel, bis(2,4-pentanedionato-kO,kO')-, (SP-4-1)- Nickelous acetylacetonate | |
| [CAS] "CASEN_3264-82-2.htm">3264-82-2 | |
| [Formula] C10H14NiO4 | |
| [Molecular Weight] 256.91000000000003 | |
| [EINECS] 221-875-7 | |
| [RTECS] SA2100000 | |
| [RTECS Class] Other | |
| [Merck] 12,6584 | |
| [Beilstein/Gmelin] 4157970 | |
| [EC Class] harmful, sensitizing | |
| [Small spills/leaks] Sweep up, then place into a suitable container for disposal. Provide ventilation. | |
| [Disposal Code] 15 | |
| [Stability] Stable under normal temperatures and pressures. | |
| [Incompatibilities] Strong oxidizing agents, moisture. | |
| [Decomposition] Carbon monoxide, carbon dioxide, 2,4-pentanedione, nickel oxide, acrid smoke and fumes, nickel. | |
| [UN Number] 3282 | |
| [HS Code] 2942 00 00 |
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