[Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Non-combustible, substance itself does not burn but may decompose upon heating to produce irritating, corrosive and/or toxic fumes. Extinguishing media: Substance is noncombustible; use agent most appropriate to extinguish surrounding fire. | |
[Fire Potential] Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. | |
[Ingestion] Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately. | |
[Inhalation] Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration. | |
[Skin] Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. | |
[Eyes] Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. | |
[Storage] Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. | |
[Handling] Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with skin and eyes. Avoid ingestion and inhalation. | |
[Inhalation] Causes respiratory tract irritation. May cause allergic respiratory reaction. | |
[Skin] Causes skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. May cause dermatitis. | |
[Eyes] Causes eye irritation. | |
[Ingestion] Causes gastrointestinal irritation with nausea, vomiting and diarrhea. | |
[Hazards] Contact with metals may evolve flammable hydrogen gas. | |
[UN (DOT)] 2811 | |
[Personal Protection] Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. | |
[Respirators] Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. | |
[Exposure Effects] Prolonged or repeated skin contact may cause sensitization dermatitis and possible destruction and/or ulceration. May cause respiratory tract cancer. May cause cancer according to animal studies. | |
[Exposure limit(s)] TLV (as Ni): ppm; 0.05 mg/m3 (ACGIH 1990-1991). | |
[Poison Class] 3 | |
[Appearance] Green rhombohedral crystals. | |
[Solubility in water] Insoluble | |
[Density] 3.67 g/cm3 | |
[Heat Of Vaporization] | |
[Usage] Chemical intermediate for nickel oxide, nickel powder, nickel catalysts. | |
[Vapor Density] N/R | |
[Product Name] Nickelous carbonate | |
[Synonyms] Nickel(II) carbonate Nickelous carbonate | |
[CAS] "CASEN_3333-67-3.htm">3333-67-3 | |
[Formula] CNiO3 | |
[Molecular Weight] 118.72 | |
[EINECS] 222-068-2 | |
[RTECS] QR6200000 | |
[RTECS Class] Tumorigen; Mutagen | |
[Beilstein/Gmelin] 8542 (G) | |
[EC Index Number] 028-010-00-0 | |
[EC Class] Carcinogenic Category 3; Harmful; Sensitising; Dangerous for the Environment | |
[Small spills/leaks] Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation. | |
[Stability] Stable under normal temperatures and pressures. | |
[Incompatibilities] Strong oxidizing agents. | |
[Decomposition] Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nickel oxide. | |
[Combustion Products] Toxic gases and vapors (such as nickel carbonyl) may be released in a fire involving nickel. | |
[UN Number] 2811 | |
[Hazard Class] 6.1 | |
[Packing Group] I; II; III |