| [Fire Fighting] Wear a self-contained breathing apparatus with a full facepiece operated in the positive pressure demand mode with appropriate turn-out gear and chemical resistant personal protective equipment. Extinguish fire using regular foam, water fog, carbon dioxide or sand. | |
| [Ingestion] First aid is not normally required. If symptoms develop, seek medical attention. | |
| [Inhalation] If symptoms develop, move individual away from exposure and into fresh air. If symptoms persist, seek medical attention. If breathing is difficult, administer oxygen. Keep person warm and quiet; seek immediate medical attention. | |
| [Skin] Remove contaminated clothing. Wash exposed area with soap and water. If symptoms persist, seek medical attention. Launder clothing before reuse. | |
| [Eyes] If symptoms develop, immediately move individual away from exposure and into fresh air. Flush eyes gently with water for at least 15 minutes while holding eyelids apart; seek immediate medical attention. | |
| [Storage] Store in a cool, dry location (< 25 C). | |
| [Handling] Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed. | |
| [Inhalation] Metal fume fever, wheezing and rales have been reported in workers exposed to fine copper dust. Dyspnea has developed after oral copper exposure. Pulmonary edema and alveolar inflammation have been noted in animals. | |
| [Skin] Skin exposure can produce in severe irritation, itching, erythema, dermatitis and eczema; systemic toxicity may result. | |
| [Eyes] Dust can cause eye irritation. Symptoms include stinging, tearing, redness, and swelling of eyes. | |
| [Ingestion] Gastroenteritis with vomiting may occur after ingestion of some copper salts. Mucosal erosions, a metallic taste, burning epigastric sensation and diarrhea may also occur. | |
| [Hazards] Dusts can form explosive mixtures in air. | |
| [Personal Protection] Wear safety glasses in compliance with OSHA regulations. Wear resistant gloves such as latex, To prevent repeated or prolonged skin contact, wear impervious clothing and boots. | |
| [Respirators] 3M Dust respirator No. 8710 or 9900 is recommended or a NIOSH/MSHA jointly approved dust respirator. | |
| [Exposure Effects] Increased temperature may be noted in some cases. Abnormally low blood pressure may occur. Mental status may be depressed. | |
| [Exposure limit(s)] OSHA: PEL (8 h TWA): 1 mg/m3. | |
| [Appearance] Light blue crystalline powder. Odorless. | |
| [Solubility in water] soluble | |
| [Melting Point] 155-157 | |
| [Usage] Fungicide. | |
| [Product Name] D-Gluconic acid copper(II) salt | |
| [Synonyms] Copper (2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanoate Copper, bis(D-gluconato-kO1,kO2)- Gluconic acid, copper(2+) salt | |
| [CAS] "CASEN_527-09-3.htm">527-09-3 | |
| [Formula] C12H22CuO14 | |
| [Molecular Weight] 453.84 | |
| [EINECS] 208-408-2 | |
| [RTECS] LZ5058000 | |
| [RTECS Class] Other | |
| [Merck] 12,2706 | |
| [Beilstein/Gmelin] NA | |
| [Small spills/leaks] Small Spill - Sweep up material for disposal or recovery. Large Spill - Shovel material into containers. Thoroughly sweep area of spill to clean up any residual material. | |
| [Incompatibilities] Acetylenes, reactive metals such as aluminum and magnesium. | |
| [Stability] Stable at normal temperatures and pressures. | |
| [Decomposition] Oxides of carbon. |
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