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3-Bromoaniline

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[Flash Point]

101
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
[Fire Potential]

Combustible material: may burn but does not ignite readily.
[Ingestion]

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
[Inhalation]

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
[Skin]

Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
[Eyes]

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
[Storage]

Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Refrigerator/flammables.
[Handling]

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
[Inhalation]

May cause respiratory tract irritation. May cause methemoglobinemia, cyanosis, convulsions, tachycardia, dyspnea, and death. Methemoglobinemia is characterized by dizziness, drowsiness, headache, breath shortness, cyanosis with bluish skin, rapid heart rate and chocolate-brown blood. Inhalation of aniline causes anoxia due to the formation of methemoglobinemia.
[Skin]

May cause skin irritation. May be absorbed through the skin. If absorbed, causes symptoms similar to inhalation.
[Eyes]

May cause severe eye irritation.
[Ingestion]

May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
[Hazards]

When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
[EC Risk Phrase]

R 20/21/22 33
[EC Safety Phrase]

S 28 36/37
[UN (DOT)]

2810
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
[Respirators]

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
[Exposure Effects]

May cause cancer according to animal studies. May cause reproductive and fetal effects.
[Appearance]

Yellow-brown liquid.
[Solubility in water]

Insoluble
[Melting Point]

16
[Boiling Point]

251
[Vapor Pressure]

0.02 (25 C)
[Density]

1.5928 g/cm3 (14 C)
[pKa/pKb]

10.48 (pKb)
[Partition Coefficient]

2.1
[Heat Of Vaporization]

48.8 kJ/mol
[Refractive Index]

1.6209 (14.9 C)
[Product Name]

m-Bromoaniline
[Synonyms]

1-Amino-3-bromobenzene
3-Amino-1-bromobenzene
3-Bromoaniline
3-Bromobenzenamine
[CAS]

"CASEN_591-19-5.htm">591-19-5
[Formula]

C6H6BrN
[Molecular Weight]

172.03
[EINECS]

209-704-4
[RTECS]

CX9855300
[RTECS Class]

Other
[Beilstein/Gmelin]

742028
[Beilstein Reference]

4-12-00-01491
[EC Class]

toxic, dangerous for the environment
[Small spills/leaks]

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Provide ventilation.
[Disposal Code]

9
[Incompatibilities]

Acids, acid chlorides, acid anhydrides, chloroformates, strong oxidizing agents.
[Stability]

Stable under normal temperatures and pressures.
[Decomposition]

Nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen bromide.
[Combustion Products]

Fire may produce irritating, corrosive and/or toxic gases.
[UN Number]

2810
[Hazard Class]

6.1
[Packing Group]

I; II; III
[HS Code]

2921 42 10