| [Flash Point] 9 | |
| [Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Extinguishing media: Do NOT use water directly on fire. Use water spray to cool fire-exposed containers. Use foam, dry chemical, or carbon dioxide. Water may be ineffective. Do NOT use straight streams of water. | |
| [Fire Potential] HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. | |
| [Ingestion] Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. | |
| [Inhalation] Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. | |
| [Skin] Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. | |
| [Eyes] Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. | |
| [Storage] Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area. Refrigerator (approx 4 C). Store protected from light. | |
| [Handling] Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Store protected from light. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. | |
| [Inhalation] Causes respiratory tract irritation. Vapors may cause dizziness or suffocation. Can produce delayed pulmonary edema. May cause burning sensation in the chest. | |
| [Skin] Causes skin irritation. May cause cyanosis of the extremities. | |
| [Eyes] Causes eye irritation. Lachrymator. May cause chemical conjunctivitis and corneal damage. | |
| [Ingestion] May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Ingestion of large amounts may cause CNS depression. | |
| [Hazards] Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. | |
| [EC Risk Phrase] R 11 36/37 42/43 | |
| [EC Safety Phrase] S 16 23 26 36/37/39 45 | |
| [UN (DOT)] 1993 | |
| [Personal Protection] Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. | |
| [Respirators] A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. | |
| [Exposure Effects] Prolonged or repeated skin contact may cause dermatitis. Effects may be delayed. | |
| [Appearance] Clear colorless to faint yellow liquid. | |
| [Boiling Point] 98 | |
| [Density] 1.355 g/cm3 (0 C) | |
| [Vapor Density] 4.66 | |
| [Refractive Index] 1.4622 (20 C) | |
| [Product Name] 4-Bromo-1-butene | |
| [Synonyms] 4-Bromobut-1-ene | |
| [CAS] "CASEN_5162-44-7.htm">5162-44-7 | |
| [Formula] C4H7Br | |
| [Molecular Weight] 135.01 | |
| [EINECS] 225-937-4 | |
| [Beilstein/Gmelin] 1098377 | |
| [Beilstein Reference] 4-01-00-00775 | |
| [EC Class] highly flammable, irritant, sensitizing | |
| [Small spills/leaks] Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors. | |
| [Stability] Stable under normal temperatures and pressures. Light sensitive. | |
| [Incompatibilities] Strong oxidizing agents, strong bases. | |
| [Decomposition] Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen bromide. | |
| [Combustion Products] Fire may produce irritating, corrosive and/or toxic gases. | |
| [UN Number] 1993 | |
| [Hazard Class] 3 | |
| [Packing Group] I; II; III | |
| [HS Code] 2903 30 36 |
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