| [Flash Point] 53 | |
| [Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Extinguishing media: Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water. In case of fire, use carbon dioxide, dry chemical powder or appropriate foam. | |
| [Fire Potential] HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. | |
| [Ingestion] Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. | |
| [Inhalation] Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. | |
| [Skin] Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. | |
| [Eyes] Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. | |
| [Storage] Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area. | |
| [Handling] Use only in a well ventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid contact with heat, sparks and flame. Do not ingest or inhale. Use only in a chemical fume hood. Wash clothing before reuse. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Do not breathe vapors. | |
| [Inhalation] Causes respiratory tract irritation. Vapors may cause dizziness or suffocation. May cause burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Can produce delayed pulmonary edema. | |
| [Skin] Causes severe skin irritation and possible burns. May cause cyanosis of the extremities. | |
| [Eyes] Lachrymator. Causes severe eye irritation and possible burns. May cause chemical conjunctivitis and corneal damage. | |
| [Ingestion] May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Ingestion of large amounts may cause CNS depression. | |
| [Hazards] Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. | |
| [EC Risk Phrase] R 10 34 36 | |
| [EC Safety Phrase] S 26 36/37/39 45 | |
| [UN (DOT)] 1993 | |
| [Personal Protection] Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. | |
| [Respirators] A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. | |
| [Exposure Effects] Effects may be delayed. | |
| [Appearance] Clear, colorless liquid. | |
| [Solubility in water] Slightly soluble | |
| [Boiling Point] 51 | |
| [Density] 1.5 g/cm3 (15 C) | |
| [Vapor Density] 5.76 | |
| [Refractive Index] 1.45 (20 C) | |
| [Product Name] 2-Bromopropionic acid methyl ester | |
| [Synonyms] Methyl DL-2-bromopropanoate Propanoic acid, 2-bromo-, methyl ester Propionic acid, 2-bromo-, methyl ester | |
| [CAS] "CASEN_5445-17-0.htm">5445-17-0 | |
| [Formula] C4H7BrO2 | |
| [Molecular Weight] 167.01 | |
| [EINECS] 226-642-3 | |
| [Beilstein/Gmelin] 1720592 | |
| [Beilstein Reference] 4-02-00-00762 | |
| [EC Class] flammable, irritant | |
| [Small spills/leaks] Cover with sand, dry lime or soda ash and place in a closed container for disposal. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors. | |
| [Disposal Code] 2 | |
| [Incompatibilities] Acids, bases, oxidizing agents, reducing agents. | |
| [Stability] Stable at room temperature in closed containers under normal storage and handling conditions. | |
| [Decomposition] Carbon monoxide, carbon dioxide, hydrogen bromide. | |
| [Combustion Products] Fire may produce irritating, corrosive and/or toxic gases. | |
| [UN Number] 1993 | |
| [Hazard Class] 3 | |
| [Packing Group] I; II; III | |
| [HS Code] 2915 90 80 |
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