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1-Bromopinacolone

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[Flash Point]

45
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing media: Use agent most appropriate to extinguish fire.
[Fire Potential]

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
[Ingestion]

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
[Inhalation]

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
[Skin]

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
[Eyes]

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
[Storage]

Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
[Handling]

Wash thoroughly after handling. Use only in a well ventilated area. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
[Ingestion]

The toxicological properties of this substance have not been fully investigated.
[Inhalation]

The toxicological properties of this substance have not been fully investigated.
[Skin]

No information regarding skin irritation and other potential effects was found.
[Eyes]

Lachrymator.
[Hazards]

Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.
[EC Risk Phrase]

R 37/38 41
[EC Safety Phrase]

S 26 36/37/39
[UN (DOT)]

1224
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
[Respirators]

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
[Appearance]

Colorless to light yellow liquid.
[Solubility in water]

Insoluble
[Melting Point]

76
[Boiling Point]

47 - 49 (1 torr)
[Density]

1.3508 g/cm3 (0 C)
[Refractive Index]

1.4632 (20 C)
[Product Name]

Bromomethyl tert-butyl ketone
[Synonyms]

1-Bromo-3,3-dimethyl-2-butanone
1-Bromopinacolin
2-Butanone, 1-bromo-3,3-dimethyl
alpha-Bromopinacolone
Bromomethyl-tert-butyl-ketone
Bromopinacolin
[CAS]

"CASEN_5469-26-1.htm">5469-26-1
[Formula]

C6H11BrO
[Molecular Weight]

179.05
[EINECS]

226-794-0
[RTECS]

EL7010000
[RTECS Class]

Other
[Beilstein/Gmelin]

506485
[Beilstein Reference]

4-01-00-03314
[Small spills/leaks]

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Remove all sources of ignition. Use a spark-proof tool.
[Stability]

No data.
[Incompatibilities]

Strong oxidizing agents.
[Decomposition]

Carbon monoxide, carbon dioxide, hydrogen bromide.
[Combustion Products]

Fire may produce irritating, corrosive and/or toxic gases.
[UN Number]

1224
[Hazard Class]

3
[Packing Group]

I; II; III