| [Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Reacts violently with water giving off flammable gas which may explode. Dusts at sufficient concentrations can form explosive mixtures with air. Extinguishing media: Use dry chemical. | |
| [Fire Potential] Container headspace may contain flammable hydrogen gas under pressure which can ignite explosively. Contact with concentrated acids or excessive heat may cause flash fire due to liberation of flammable hydrogen gas which can ignite explosively. Flammable solid. | |
| [Ingestion] Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid. | |
| [Inhalation] Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. | |
| [Skin] Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. | |
| [Eyes] Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. | |
| [Storage] Store in a cool, dry place. Store in a tightly closed container. Keep under a nitrogen blanket. Flammables-area. | |
| [Handling] Wash thoroughly after handling. Wash hands before eating. Use with adequate ventilation. Do not allow water to get into the container because of violent reaction. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. | |
| [Ingestion] Causes gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated. | |
| [Inhalation] Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. | |
| [Skin] Causes skin irritation. | |
| [Eyes] Causes eye irritation. May cause irreversible eye injury. Vapor may cause blurred vision with bluish haze and halos around bright objects. | |
| [Hazards] Contact with metals may evolve flammable hydrogen gas. | |
| [EC Risk Phrase] R 11 36/37/38 | |
| [EC Safety Phrase] S 3/7/9 16 26 43 | |
| [UN (DOT)] 2811 | |
| [Personal Protection] Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. | |
| [Respirators] Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. | |
| [Appearance] Clear colorless to slightly yellow solid. Slight amine odor. | |
| [Solubility in water] 80 g/L | |
| [Melting Point] 98.7 - 99.9 | |
| [Usage] Aldehyde and ketone reduction reactions, reductive aminations, electrodeless plating and reduction of metal salts. | |
| [Product Name] Morpholineborane | |
| [Synonyms] Borane, compound with morpholine Morpholine borane Morpholine, boron complex Morpholine, compd. with borane (1:1) Morpholineborane MPB | |
| [CAS] "CASEN_4856-95-5.htm">4856-95-5 | |
| [Formula] C4H8BNO | |
| [Molecular Weight] 96.92 | |
| [EINECS] 225-450-7 | |
| [RTECS] QD8530000 | |
| [RTECS Class] Drug | |
| [Beilstein/Gmelin] 1010179 (G) | |
| [Small spills/leaks] Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. | |
| [Incompatibilities] Acids, acid chlorides, acid anhydrides, alcohols, and moist air or water. Contact with concentrated acids or excessive heat may cause flash fire due to liberation of flammable hydrogen gas which can ignite explosively. | |
| [Stability] Stable under normal temperatures and pressures. | |
| [Decomposition] Nitrogen oxides, carbon monoxide, carbon dioxide, oxides of boron, borane, hydrogen gas. | |
| [Combustion Products] Fire may produce irritating, corrosive and/or toxic gases. | |
| [UN Number] 2811 | |
| [Hazard Class] 6.1 | |
| [Packing Group] I; II; III |
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