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Pinacol

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[Flash Point]

77
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. Use agent most appropriate to extinguish fire.
[Ingestion]

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
[Inhalation]

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
[Skin]

Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
[Eyes]

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
[Storage]

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
[Handling]

Wash thoroughly after handling. Avoid contact with skin and eyes. Keep container tightly closed. Avoid ingestion and inhalation. Use only in a chemical fume hood. Wash clothing before reuse.
[Ingestion]

May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
[Inhalation]

May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
[Skin]

May cause skin irritation.
[Eyes]

May cause eye irritation.
[EC Risk Phrase]

R 36/38
[EC Safety Phrase]

S 26 36
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear a chemical apron. Wear appropriate protective clothing to prevent skin exposure.
[Respirators]

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
[Appearance]

White solid.
[Solubility in water]

Very soluble
[Melting Point]

40 - 41
[Boiling Point]

157 - 159
[Vapor Pressure]

0.38 (25 C)
[Density]

0.967 g/cm3 (15 C)
[Partition Coefficient]

-.3
[Heat Of Vaporization]

47.8 kJ/mol
[Usage]

Used with borane and boron trichloride to produce useful synthetic intermediate such as pinacol borane.
[Refractive Index]

1.4426 (16 C)
[Product Name]

2,3-Dimethyl-2,3-butanediol
[Synonyms]

1,1,2,2-Tetramethylethylene glycol
2,3-Dihydroxy-2,3-dimethylbutane
2,3-Dimethyl-2,3-butanediol
2,3-Dimethyl-2,3-dihydroxybutane
Pinacone
Tetramethylethylene glycol
[CAS]

"CASEN_76-09-5.htm">76-09-5
[Formula]

C6H14O2
[Molecular Weight]

118.17
[EINECS]

200-933-5
[RTECS]

EK1720000
[RTECS Class]

Primary Irritant
[Merck]

12,7593
[Beilstein/Gmelin]

1340501
[Beilstein Reference]

4-01-00-02575
[Small spills/leaks]

Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.
[Incompatibilities]

Oxidizing materials, strong acids, strong bases.
[Stability]

Stable under normal temperatures and pressures.
[Decomposition]

Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.