| [Flash Point] 8.5 | |
| [Autoignition] > 400 | |
| [Autoignition] 325 | |
| [Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Containers may explode in the heat of a fire. Water Reactive. Reacts with water to form acidic gases which when in contact with metal may liberate flammable and/or hydrogen gas. Extinguishing media: Do NOT use water directly on fire. Use dry chemical, carbon dioxide, or alcohol-resistant foam. Do NOT get water inside containers. Do NOT use straight streams of water. Cool containers with flooding quantities of water until well after fire is out. | |
| [Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Runoff from fire control or dilution water may cause pollution. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use agent most appropriate to extinguish fire. | |
| [Upper exp. limit] 8.2 | |
| [Lower exp. limit] 2.1 | |
| [Fire Potential] Flammable/combustible material. | |
| [Fire Potential] This material is probably combustible. | |
| [Ingestion] If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. | |
| [Ingestion] May cause digestive tract disturbances. Ingestion of large amounts may cause CNS depression. Ingestion of large amounts may cause pain, constipation or diarrhea. | |
| [Ingestion] Never give anything by mouth to an unconscious person. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Get medical aid if irritation or symptoms occur. | |
| [Inhalation] Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear. | |
| [Inhalation] Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. | |
| [Inhalation] May cause respiratory tract irritation. | |
| [Skin] May cause skin irritation. | |
| [Skin] Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Get medical aid if symptoms occur. | |
| [Skin] Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Discard contaminated clothing in a manner which limits further exposure. | |
| [Eyes] May cause eye irritation. | |
| [Eyes] Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. | |
| [Eyes] Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. If irritation develops, get medical aid. | |
| [Storage] Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. | |
| [Storage] Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from light. | |
| [Handling] Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. Store protected from light. | |
| [Handling] Wash thoroughly after handling. Use with adequate ventilation. Ground and bond containers when transferring material. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. | |
| [Ingestion] The toxicological properties of this substance have not been fully investigated. | |
| [Inhalation] The toxicological properties of this substance have not been fully investigated. | |
| [Skin] Causes skin burns. | |
| [Eyes] Causes eye burns. | |
| [Hazards] May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. May polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. | |
| [EC Risk Phrase] R 11 35 | |
| [EC Risk Phrase] R 36/38 50/53 | |
| [EC Safety Phrase] S 16 23 26 36 45 | |
| [EC Safety Phrase] S 37 60 61 | |
| [UN (DOT)] 2395 | |
| [UN (DOT)] 3077 | |
| [Personal Protection] Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. | |
| [Personal Protection] Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. | |
| [Respirators] Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. | |
| [Exposure Effects] Prolonged or repeated exposure can cause psychic abnormalities such as anxiety, depression and excitability. | |
| [Poison Class] 4 | |
| [Appearance] A colorless liquid. | |
| [Appearance] Yellow powder with a slight odor. | |
| [Solubility in water] Insoluble | |
| [Solubility in water] Reacts | |
| [Melting Point] -90 | |
| [Melting Point] 194 | |
| [Boiling Point] 91 | |
| [Boiling Point] 270 | |
| [Vapor Pressure] 53 (20 C) | |
| [Vapor Pressure] 0.007 (25 C) | |
| [Density] 1.017 g/cm3 (20 C) | |
| [Density] 1.97 g/cm3 (20 C) | |
| [Partition Coefficient] 1.49 | |
| [Partition Coefficient] 1.39 | |
| [Heat Of Vaporization] 50.8 kJ/mol | |
| [Heat Of Combustion] -2173 kJ/mol | |
| [Usage] In manufacture of chloranil electrodes for ph measurements, to manufacture compound used in dye industry, as reagent for pamaquine (plasmochin) in urine (blue color). Fungicide. | |
| [Usage] Used to make other chemicals. | |
| [Vapor Density] 8.5 | |
| [Vapor Density] 3.7 | |
| [Refractive Index] 1.4079 (20 C) | |
| [Product Name] 2-Methylpropanoyl chloride | |
| [Synonyms] 2,3,5,6-Tetrachloro-2,5-cyclohexadiene-1,4-dione 2,3,5,6-Tetrachloro-p-benzoquinone 2-Methylpropanoyl chloride Tetrachloro-p-benzoquinone Tetrachloro-p-quinone | |
| [CAS] "CASEN_118-75-2.htm">118-75-2 | |
| [CAS] "CASEN_79-30-1.htm">79-30-1 | |
| [Formula] C4H7ClO | |
| [Formula] C6Cl4O2 | |
| [Molecular Weight] 106.55 | |
| [Molecular Weight] 245.88 | |
| [EINECS] 201-194-1 | |
| [EINECS] 204-274-4 | |
| [RTECS] DK6825000 | |
| [RTECS] UC3944000 | |
| [RTECS Class] Primary Irritant | |
| [RTECS Class] Agricultural Chemical and Pesticide; Tumorigen; Drug; Mutagen | |
| [Merck] 13,2088 | |
| [Beilstein/Gmelin] 393006 | |
| [Beilstein/Gmelin] 605393 | |
| [Beilstein Reference] 4-02-00-00852 | |
| [Beilstein Reference] 4-07-00-02083 | |
| [EC Index Number] 602-066-00-1 | |
| [EC Index Number] 607-140-00-7 | |
| [EC Class] Highly flammable; Corrosive | |
| [EC Class] Irritant; Dangerous for the Environment | |
| [Small spills/leaks] Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors. Water spray may reduce vapor but may not prevent ignition in closed spaces. | |
| [Small spills/leaks] Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation. | |
| [Disposal Code] 11 | |
| [Disposal Code] 3 | |
| [Incompatibilities] Oxidizing agents, strong bases, alcohols. | |
| [Stability] Stable under normal temperatures and pressures. | |
| [Incompatibilities] Strong oxidizing agents. | |
| [Decomposition] Hydrogen chloride, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide. | |
| [Decomposition] Hydrogen chloride, phosgene, carbon monoxide, carbon dioxide. | |
| [Combustion Products] Fire will produce irritating, corrosive and/or toxic gases. | |
| [UN Number] 2395 | |
| [UN Number] 3077 | |
| [Hazard Class] 3 | |
| [Packing Group] II | |
| [HS Code] 2914 70 90 | |
| [HS Code] 2915 90 80 |
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