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2-Bromoaniline

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[Flash Point]

91
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Runoff from fire control or dilution water may cause pollution. Extinguishing media: For small fires, use dry chemical, carbon dioxide, or water spray. For large fires, use dry chemical, carbon dioxide, alcohol-resistant foam, or water spray. Cool containers with flooding quantities of water until well after fire is out.
[Fire Potential]

Combustible material: may burn but does not ignite readily.
[Ingestion]

Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
[Inhalation]

Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
[Skin]

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
[Eyes]

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
[Storage]

Store in a cool, dry place.
[Handling]

Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
[Inhalation]

May cause methemoglobinemia, cyanosis, convulsions, tachycardia, dyspnea, and death. May cause liver and kidney damage. May cause respiratory tract irritation. May cause cardiac abnormalities.
[Skin]

May cause skin irritation.
[Eyes]

May cause eye irritation.
[Ingestion]

May cause irritation of the digestive tract. May cause liver and kidney damage. May cause cardiac disturbances. May cause methemoglobinemia, cyanosis, convulsions, and death. May cause central nervous system depression.
[Hazards]

When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
[EC Risk Phrase]

R 20/21/22 33
[EC Safety Phrase]

S 28 36/37
[UN (DOT)]

2810
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves and clothing to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
[Respirators]

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
[Exposure Effects]

May cause methemoglobinemia, which is characterized by chocolate-brown colored blood, headache, weakness, dizziness, breath shortness, cyanosis, rapid heart rate, unconsciousness and possible death. Effects may be delayed.
[Appearance]

Clear yellow solid or liquid.
[Solubility in water]

Insoluble
[Melting Point]

27 - 31
[Boiling Point]

229
[Vapor Pressure]

0.08 (25 C)
[Density]

1.86 g/cm3
[pKa/pKb]

11.46 (pKb)
[Partition Coefficient]

2.19
[Heat Of Vaporization]

46.4 kJ/mol
[Vapor Density]

5.9
[Refractive Index]

1.6113 (20 C)
[Product Name]

o-Bromoaniline
[Synonyms]

2-Amino-1-bromobenzene
2-Bromoaniline
2-Bromobenzenamine
-Aminobromobenzene
[CAS]

"CASEN_615-36-1.htm">615-36-1
[Formula]

C6H6BrN
[Molecular Weight]

172.03
[EINECS]

210-421-3
[Beilstein/Gmelin]

742062
[Beilstein Reference]

4-12-00-01487
[EC Class]

toxic, dangerous for the environment
[Small spills/leaks]

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Provide ventilation.
[Incompatibilities]

Acids - acid chlorides - acid anhydrides - chloroformates - strong oxidizing agents.
[Stability]

Stable under normal temperatures and pressures.
[Decomposition]

Nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen bromide, nitrogen.
[Combustion Products]

Fire may produce irritating, corrosive and/or toxic gases.
[UN Number]

2810
[Hazard Class]

6.1
[Packing Group]

I; II; III
[HS Code]

2921 42 10