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3-Methylpiperidine

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[Flash Point]

17
[Fire Fighting]

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Water may be ineffective. Material is lighter than water and a fire may be spread by the use of water. Containers may explode in the heat of a fire. Extinguishing media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Use agent most appropriate to extinguish fire. Do NOT use straight streams of water.
[Fire Potential]

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
[Ingestion]

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
[Inhalation]

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
[Skin]

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
[Eyes]

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
[Storage]

Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.
[Handling]

Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid contact with heat, sparks and flame. Use with adequate ventilation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
[Ingestion]

May cause irritation of the digestive tract.
[Inhalation]

May cause respiratory tract irritation. Vapors may cause dizziness or suffocation.
[Skin]

May cause skin irritation.
[Eyes]

May cause eye irritation.
[Hazards]

Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.
[EC Risk Phrase]

R 11 36/37/38
[EC Safety Phrase]

S 16 26 36/37/39
[UN (DOT)]

1993
[Personal Protection]

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
[Respirators]

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
[Appearance]

A colorless liquid with a characteristic odor.
[Solubility in water]

Very soluble
[Melting Point]

-24
[Boiling Point]

125
[Vapor Pressure]

12 (25 C)
[Density]

0.8635 g/cm3 (0 C)
[pKa/pKb]

2.72 (pKb)
[Partition Coefficient]

1.42
[Heat Of Vaporization]

36.3 kJ/mol
[Vapor Density]

3.42
[Refractive Index]

1.45 (20 C)
[Product Name]

3-Methylpiperidine
[Synonyms]

3-Methylpiperidine
beta-Pipecoline
[CAS]

"CASEN_626-56-2.htm">626-56-2
[Formula]

C6H13N
[Molecular Weight]

99.17
[EINECS]

210-953-6
[Beilstein/Gmelin]

79807
[Beilstein Reference]

5-20-04-00100
[Small spills/leaks]

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors.
[Incompatibilities]

Acids, acid chlorides, acid anhydrides, carbon dioxide, strong oxidizing agents.
[Stability]

Stable under normal temperatures and pressures.
[Decomposition]

Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.
[Combustion Products]

Fire may produce irritating, corrosive and/or toxic gases.
[UN Number]

1993
[Hazard Class]

3
[Packing Group]

I; II; III