[Fire Fighting] Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Non-combustible, substance itself does not burn but may decompose upon heating to produce irritating, corrosive and/or toxic fumes. Extinguishing media: Substance is noncombustible; use agent most appropriate to extinguish surrounding fire. | |
[Ingestion] Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. | |
[Inhalation] Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration. | |
[Skin] Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes. | |
[Eyes] Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. | |
[Storage] Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. | |
[Handling] Wash thoroughly after handling. Wash hands before eating. Use only in a well ventilated area. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. | |
[Inhalation] Causes respiratory tract irritation. May cause allergic respiratory reaction. In rare instances, exposure may cause sensitization, resulting in inflammation of the mucous membranes and in eczematous eruptions. | |
[Skin] Causes skin irritation. May cause dermatitis. Causes nickel itch which is a dermatitis resulting from sensitization to nickel, which is characterized by skin eruptions, followed by discrete ulcers that may discharge and become crusted, or by eczema. | |
[Eyes] Causes eye irritation. | |
[Ingestion] Harmful if swallowed. Causes gastrointestinal irritation with nausea, vomiting and diarrhea. | |
[EC Risk Phrase] R 25 22 36/37/38 43 | |
[EC Safety Phrase] S 53 45 | |
[UN (DOT)] 3282 | |
[Personal Protection] Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. | |
[Respirators] Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. | |
[Exposure Effects] May cause respiratory tract cancer. May cause cancer according to animal studies. Symptoms of overexposure to nickel can cause sensitization, dermatitis, allergic asthma and pneumonitis. | |
[Exposure limit(s)] 0.1 mg/m3 TLV | |
[Appearance] Green solid. Acetic - weak odor. | |
[Boiling Point] 16 | |
[Density] 1.798 g/cm3 | |
[Product Name] Acetic acid nickel(II) salt | |
[Synonyms] Acetic acid, nickel(+2) salt, tetrahydrate Diacetatonickel tetrahydrate Nickel diacetate tetrahydrate Nickel(II) acetate tetrahydrate Nickelous acetate tetrahydrate | |
[CAS] "CASEN_6018-89-9.htm">6018-89-9 | |
[Formula] C4H14NiO8 | |
[Molecular Weight] 248.84 | |
[EINECS] 206-761-7 | |
[RTECS] QR6126000 | |
[RTECS Class] Tumorigen; Mutagen | |
[Merck] 12,6583 | |
[Beilstein/Gmelin] 3730764 | |
[Beilstein Reference] 4-02-00-00094 | |
[Small spills/leaks] Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation. | |
[Stability] Stable under normal temperatures and pressures. | |
[Incompatibilities] Strong oxidizing agents. | |
[Decomposition] Carbon monoxide, irritating and toxic gases, carbon dioxide, nickel oxide. | |
[UN Number] 3282 |